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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Kellici, Suela
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 20233D printed SrNbO2N photocatalyst for degradation of organic pollutants in watercitations
- 2023Nanostructured Al2O3/Graphene Additive in Bio-Based Lubricant: A Novel Approach to Improve Engine Performancecitations
- 2021Continuous hydrothermal flow synthesis of S-functionalised carbon quantum dots for enhanced oil recoverycitations
- 2018Greener synthesis of dimethyl carbonate using a novel tin-zirconia/graphene nanocomposite catalystcitations
- 2018Greener synthesis of butylene carbonate via CO2 utilisation using graphene-inorganic nanocomposite catalysts
- 2018Greener synthesis of 1,2-butylene carbonate from CO2 using graphene-inorganic nanocomposite catalystcitations
- 2017Greener synthesis of styrene carbonate from CO2 using graphene-inorganic nanocomposite catalysts
- 2017Greener synthesis of 1, 2 butylene carbonate from CO2 using graphene-inorganic nanocomposite catalysis
- 2016Calixarene assisted rapid synthesis of silver-graphene nanocomposites with enhanced antibacterial activitycitations
- 2014Imaging the continuous hydrothermal flow synthesis of nanoparticulate CeO2 at different supercritical water temperatures using in situ angle-dispersive diffractioncitations
- 2014Optical and photocatalytic behaviours of nanoparticles in the Ti-Zn-O binary systemcitations
Places of action
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article
Greener synthesis of 1,2-butylene carbonate from CO2 using graphene-inorganic nanocomposite catalyst
Abstract
The synthesis of 1,2-butylene carbonate (BC) from cycloaddition reaction of 1,2-butylene oxide (BO) and carbon dioxide (CO2) was investigated using several heterogeneous catalysts in the absence of organic solvent. Continuous hydrothermal flow synthesis (CHFS) has been employed as a rapid and cleaner route for the synthesis of a highly efficient graphene-inorganic heterogeneous catalyst, ceria-lanthana-zirconia/graphene nanocomposite, represented as Ce–La–Zr/GO. The heterogeneous catalysts have been characterised using transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), X-ray powder diffraction (XRD) and nitrogen adsorption/desorption (BET for measuring the surface area/pore size distribution),. Ceria- lanthana-zirconia/graphene nanocomposite catalyst (Ce–La–Zr/GO) exhibited high catalytic activity as compared to other reported heterogeneous catalysts in the absence of any organic solvent with a selectivity of 76% and 64% yield of 1,2-butylene carbonate at the reaction conditions of 408 K, 75 bar in 20 h.