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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Banat, Fawzi
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2023The curious case of polyaniline-graphene nanocomposites: a review on their application as exceptionally conductive and gas sensitive materialscitations
- 2021Sulfide remediation from wastewater using hydrothermally synthesized δ-MnO2/porous graphitic carbon as adsorbentcitations
- 2021Sulfide remediation from wastewater using hydrothermally synthesized δ-MnO 2 /porous graphitic carbon as adsorbentcitations
- 2020Catalytic hydrodeoxygenation of biomass-derived pyrolysis oil over alloyed bimetallic Ni3Fe nanocatalyst for high-grade biofuel productioncitations
- 2020Development of Polyethersulfone/α-Zirconium phosphate (PES/α-ZrP) flat-sheet nanocomposite ultrafiltration membranescitations
- 2020Catalytic hydrodeoxygenation of biomass-derived pyrolysis oil over alloyed bimetallic Ni 3 Fe nanocatalyst for high-grade biofuel productioncitations
- 2020Morphology-dependent electrochemical performance of MnO₂ nanostructures on graphene towards efficient capacitive deionizationcitations
- 2020Design of adsorption column for reclamation of methyldiethanolamine using homogeneous surface diffusion modelcitations
- 2020Chicken feathers as an intrinsic source to develop ZnS/carbon composite for Li-ion battery anode materialcitations
- 2020Chicken feathers as an intrinsic source to develop ZnS/carbon composite for Li-ion battery anode materialcitations
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article
Catalytic hydrodeoxygenation of biomass-derived pyrolysis oil over alloyed bimetallic Ni3Fe nanocatalyst for high-grade biofuel production
Abstract
<p>The design of cost-effective and high-performance bimetallic catalysts has become crucial for the effective conversion of biomass-derived pyrolysis-oil (Py-oil) into liquid biofuels. New bimetallic Ni<sub>3</sub>Fe catalysts were developed for effective hydrodeoxygenation (HDO) of Py-oil derived from date seeds. Ni<sub>3</sub>Fe catalyst showed a well-defined octagon-like morphology with a diameter of 120 nm and high saturation magnetization (Ms) of 78 emu g<sup>−1</sup> at room temperature. Py-oil was subjected to catalytic HDO processes at 250 °C for 120 min in a 10 bar H<sub>2</sub> atmosphere in the presence of Ni<sub>3</sub>Fe catalyst. Characterization results confirmed HDO of several components of Py-oil, including phenols, acids, aldehyde and ketones, sugars and aromatic hydrocarbons over the surfaces of Ni<sub>3</sub>Fe catalyst. The obtained upgraded Py-oil (HDO Py-oil) showed the highest hydrocarbons content of 23.77%, higher heating value (HHV) of 36.78 MJ kg<sup>−1</sup>, and lower content of water, total acid number, and viscosity than fresh Py-oil. Bimetallic Ni<sub>3</sub>Fe catalyst resulted in better HDO performance and re-usability for five consecutive cycles than recently reported monometallic or noble metal nanocatalysts. Plausible reaction pathways for the formation of major components including ethane, ethyl acetate, 2,5-dimethylfuran, D-sorbitol, methylcyclohexane, furfural alcohol, and 1,5-pentane diols are discussed. Results demonstrate that this simple and active bimetallic catalytic system leads to a cutting-edge liquid biofuels production pathway in the future.</p>