People | Locations | Statistics |
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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Roussel, Pascal
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (65/65 displayed)
- 2024Nanofeather ruthenium nitride electrodes for electrochemical capacitorscitations
- 2024Seawater corrosive engineering assisted in-situ room temperature synthesis of Ni/Co/Fe trimetallic composition to achieve polyester plastics upgrading and green hydrogen productioncitations
- 2024Thermal characterization of Ge-rich GST thin films for phase change memories by Raman thermometrycitations
- 2023Effect of C deuteration in forming isotopic polymorph of glycine silver nitratecitations
- 2023Construction of desert rose flower-shaped NiFe LDH-Ni3S2 heterostructures via seawater corrosion engineering for efficient water-urea splitting and seawater utilizationcitations
- 2023High Throughput Characterization Methods at the Wafer Scale for Sputtered Films Used in Micro-Supercapacitors and Li-Ion Micro-Batteries
- 2023Photoelectrochemical properties of copper pyrovanadate (Cu 2 V 2 O 7 ) thin films synthesized by pulsed laser depositioncitations
- 2023Major Improvement in the Cycling Ability of Pseudocapacitive Vanadium Nitride Films for Micro‐Supercapacitorcitations
- 2022Preparation of Flower-Shaped Co-Fe Layer Double Hydroxide Nanosheets Loaded with Pt Nanoparticles by Corrosion Engineering for Efficient Electrocatalytic Water Splittingcitations
- 2022Preparation of Flower-Shaped Co-Fe Layer Double Hydroxide Nanosheets Loaded with Pt Nanoparticles by Corrosion Engineering for Efficient Electrocatalytic Water Splittingcitations
- 2022Sputtered (Fe,Mn)<sub>3</sub>O<sub>4</sub> Spinel Oxide Thin Films for Micro-Supercapacitorcitations
- 20220D/2D Co3O4/Ti3C2 MXene Composite: A Dual-Functional Electrocatalyst for Energy-Saving Hydrogen Production and Urea Oxidationcitations
- 2022Development of a TiO2/sepiolite photocatalyst for the degradation of a persistent organic pollutant in aqueous solutioncitations
- 20223D LiMn 2 O 4 Thin Film Deposited by ALD: A Road toward High‐Capacity Electrode for 3D Li‐Ion Microbatteriescitations
- 2022Thin-Film Stabilization of a Ferroelectric Orthorhombic α-Pr 2 WO 6 Polymorphcitations
- 20223D LiMn<sub>2</sub>O<sub>4</sub> Thin Film Deposited by ALD: A Road toward High‐Capacity Electrode for 3D Li‐Ion Microbatteriescitations
- 2022[Frontispiece] In Situ Liquid Electrochemical TEM Investigation of LiMn<sub>1.5</sub>Ni<sub>0.5</sub>O<sub>4</sub> Thin Film Cathode for Micro‐Battery Applications (Small Methods 2/2022)citations
- 2022Understanding the p-doping of spiroOMeTAD by tris(pentafluorophenyl)boranecitations
- 2022In Situ Liquid Electrochemical TEM Investigation of LiMn1.5Ni0.5O4 Thin Film Cathode for Micro‐Battery Applicationscitations
- 2022Sputtered (Fe,Mn) 3 O 4 Spinel Oxide Thin Films for Micro-Supercapacitorcitations
- 2022[Frontispiece] In Situ Liquid Electrochemical TEM Investigation of LiMn 1.5 Ni 0.5 O 4 Thin Film Cathode for Micro‐Battery Applications (Small Methods 2/2022)citations
- 2022Three-Dimensional TiO2 Film Deposited by ALD on Porous Metallic Scaffold for 3D Li-Ion Micro-Batteries: A Road towards Ultra-High Capacity Electrodecitations
- 2022Three-Dimensional TiO2 Film Deposited by ALD on Porous Metallic Scaffold for 3D Li-Ion Micro-Batteries: A Road towards Ultra-High Capacity Electrodecitations
- 2021Simultaneous photocatalytic Cr(VI) reduction and phenol degradation over copper sulphide-reduced graphene oxide nanocomposite under visible light irradiation: Performance and reaction mechanismcitations
- 2021Crystallization mechanism of BaO-CaO-Al<sub>2</sub>O<sub>3</sub>-SiO<sub>2</sub> (BCAS) glass thin-filmscitations
- 2021Silicon nanowire-hydrogenated TiO2 core-shell arrays for stable electrochemical micro-capacitorscitations
- 2021Sputtered LiNi0.5Mn1.5O4 Thin Films for Lithium-Ion Microbatteriescitations
- 2021Enhanced electrocatalytic activity of PtRu/nitrogen and sulphur co-doped crumbled graphene in acid and alkaline mediacitations
- 2020Ferroelectric State in an α-Nd 2 WO 6 Polymorph Stabilized in a Thin Filmcitations
- 2020High performance flexible hybrid supercapacitors based on nickel hydroxide deposited on copper oxide supported by copper foam for a sunlight-powered rechargeable energy storage systemcitations
- 2019Fast electrochemical storage process in sputtered Nb<sub>2</sub>O<sub>5</sub> porous thin filmscitations
- 2019Fast Electrochemical Storage Process in Sputtered Nb2O5 Porous Thin Filmscitations
- 2019Fast electrochemical storage process in sputtered Nb 2 O 5 porous thin filmscitations
- 2019Optical properties of Ln 2 Ti 2 O 7 (with Ln=La to Lu) thin films grown on (110)-SrTiO 3 substrates by pulsed laser depositioncitations
- 2019Fabrication of ZnCoS nanomaterial for high energy flexible asymmetric supercapacitorscitations
- 2019Microstructure and nanoscale piezoelectric/ferroelectric properties in Ln2WO6 (Ln=La and Nd) thin films grown by pulsed laser deposition on (001)-oriented SrTiO3 substrates
- 2019Microstructural study of nickel thin films by pulsed laser deposition
- 2018Microstructure and oxidation resistance of relaxed epitaxial nickel thin films grown on (100)- and (110)-SrTiO 3 substrates by pulsed laser depositioncitations
- 2018Visible light assisted oxidative coupling of benzylamines using heterostructured nanocomposite photocatalystcitations
- 2018On chip interdigitated micro-supercapacitors based on sputtered bifunctional vanadium nitride thin films with finely tuned inter- and intracolumnar porositiescitations
- 2017Sputtered titanium carbide thick film for high areal energy on chip carbon-based micro-supercapacitorscitations
- 2017Sputtered titanium carbide thick film for high areal energy on chip carbon-based micro-supercapacitorscitations
- 2017Tuning the Cation Ordering with the Deposition Pressure in Sputtered LiMn1.5Ni0.5O4 Thin Film Deposited on Functional Current Collectors for Li-Ion Microbattery Applicationscitations
- 2016Atomic Layer Deposition of Functional Layers for on Chip 3D Li-Ion All Solid State Microbatterycitations
- 2016Epitaxial growth and nanoscale electrical properties of Ce2Ti2O7thin filmscitations
- 2015Lead-Free α-La2WO6 Ferroelectric Thin Filmscitations
- 2015Novel La3Fe(MoO4)6 phase: magnetic properties and ethanol reactivitycitations
- 2015Magnetic Co 3 O 4 /reduced graphene oxide nanocomposite as a superior heterogeneous catalyst for one-pot oxidative esterification of aldehydes to methyl esterscitations
- 2014Microstructure and nanoscale piezoelectric/ferroelectric properties in Ln 2 Ti 2 O 7 (Ln=La, Pr and Nd) oxide thin films grown by pulsed laser depositioncitations
- 2014Nanostructured gadolinium-doped ceria microsphere synthesis from ion exchange resin: Multi-scale in-situ studies of solid solution formationcitations
- 2014Step-conformal deposition of TiO2 and MnO2 electrodes on advanced silicon microstructures for 3D Li-ion microbatteries and micro-supercapacitors
- 2013Sensing mechanism of hydrogen sensors based on palladium-loaded tungsten oxide (Pd-WO3)citations
- 2012Sensing mechanism of hydrogen sensors based on palladium-loaded tungsten oxide (Pd-WO3)citations
- 2012Mixed Metallic Ba(Co,Fe)X 0.2 O 3−δ (X = F, Cl) Hexagonal Perovskites: Drastic Effect of Fe-Incorporation on Structural and Electronic Featurescitations
- 2012Investigation of microstructure in ferroelectric lead-free La2Ti2O7 thin film grown on (001)-SrTiO3 substratecitations
- 2012Evidence of ferroelectricity in metastable Sm2Ti2O7 thin filmcitations
- 2011Microstructure and Nanoscale Piezoelectric/Ferroelectric Properties in La 2 Ti 2 O 7 Thin Films Grown on (110)‐Oriented Doped Nb:SrTiO 3 Substratescitations
- 2010SiO2-SnO2 glass-ceramic planar waveguides doped by rare-earth elaborated by the sol-gel process
- 2008Oxidation kinetics of Ni metallic films: formation of NiO-based resistive switching structurescitations
- 2007Layered ruthenium hexagonal perovskites: The new series [Ba2Br2-2x(CO3)x][Ban+1RunO3n+3] with n = 2, 3, 4, 5citations
- 2007Synthesis and molecular structure of [3,5–dichloro-salicylidene-thio-semicarbazido (2-)]-dimethyl-formamide-copper dimethyl-formamide-solvated and cathena poly-[3,5-dichloro-salicylidene-thio-semicarbazido(2-)] -dimethyl -sulfoxide-copper (II)
- 2007Structural investigation of composite phases Ba1+x[(NaxMn1−x)O3] with x= 2/7, 5/17 and 1/3 ; exotic Mn4.5+ valence in perovskite-like structure
- 2007Oxygen diffusion mechanisms in two series of oxide ion conductors: BIMEVOX and Brownmillerite materials
- 2007Magnetic structure of Ba7Co6BrO17
- 2006New heteropolynuclear Bi-Sm and Bi-Ho complexes with ethylenediaminetetraacetic acid
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article
Understanding the p-doping of spiroOMeTAD by tris(pentafluorophenyl)borane
Abstract
The solid-state organization of photoabsorber, hole and electron transporting layers, and interfaces between them plays an important role in governing the performance and stability of emerging optoelectronic devices such as perovskite solar cells (PSCs). The molecular organic semiconductor (OSC) 2,2′,7,7′-tetrakis [N,N-di(4-methoxyphenyl)amino]-9,9′-spirobifluorene (spiroOMeTAD) is a promising hole-transporting material (HTM) for PSCs, which is p-doped by molecular dopants to augment the charge carrier mobility. Here, the p-type doping of spiroOMeTAD by tris(pentafluorophenyl)borane (BCF) is investigated by a combination of techniques including optical spectroscopy, X-ray diffraction, Fourier transform infrared (FTIR), solid-state (ss)NMR, and electron paramagnetic resonance (EPR) spectroscopy. BCF molecules interact with traces of water molecules to form BCF-water complexes. Optical spectroscopy analysis suggests that the BCF/BCF-water complexes oxidize spiroOMeTAD molecules and facilitate p-type doping of spiroOMeTAD molecules. The different distributions of BCF and BCF-water molecules in doped spiroOMeTAD are characterized by FTIR and 11B NMR spectroscopy. An NMR crystallography approach which combines two-dimensional (2D) ssNMR and crystallography modeling is employed to unravel the packing interactions in spiroOMeTAD, and this analysis is extended to probe the morphological and structural changes in spiroOMeTAD:BCF blends. The hyperfine interactions are characterized by 2D hyperfine sub-level correlation (HYSCORE) spectroscopy. In this way, insight into the complex spiroOMeTAD:BCF blend morphology is obtained and compared for different dopant concentrations. Molecular-level analysis of doped HTMs enabled by this study has much wider relevance for further investigation, for example, chemical design and interfacial engineering of p-type doped HTMs for stable and efficient hybrid perovskite photovoltaics. ; 424;