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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ehrenberg, Helmut
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (51/51 displayed)
- 2024Influence of Process Parameters on the Electrochemical Properties of Hierarchically Structured Na₃V₂(PO₄)₃/C Composites
- 2024Modification of AI surface via acidic treatment and its impact on plating and strippingcitations
- 2024Modification of Al Surface via Acidic Treatment and its Impact on Plating and Strippingcitations
- 2024Hindered Aluminum Plating and Stripping in Urea/NMA/Al(OTF)$_3$ as a Cl-Free Electrolyte for Aluminum Batteries
- 2024Understanding the Electrochemical Reaction Mechanism of the Co/Ni Free Layered Cathode Material P2–Na$_{2/3}$Mn$_{7/12}$Fe$_{1/3}$Ti$_{1/12}$O$_{2}$ for Sodium-Ion Batteries
- 2024The Role of Surface Free Energy in Binder Distribution and Adhesion Strength of Aqueously Processed LiNi$_{0.5}$ Mn$_{1.5}$O$_{4}$ Cathodes
- 2024Thermal Structural Behavior of ElectrochemicallyLithiated Graphite (LixC6) Anodes in Li‐ion Batteriescitations
- 2024Understanding the Electrochemical Reaction Mechanism of the Co/Ni Free Layered Cathode Material P2–Na$_{2/3}$Mn$_{7/12}$Fe$_{1/3}$Ti$_{1/12}$O$_2$ for Sodium-Ion Batteriescitations
- 2023Modification of Al Surface via Acidic Treatment and its Impact on Plating and Stripping
- 2023Structure, site symmetry and spin-orbit coupled magnetism of a Ca12Al14O33 mayenite single crystal substituted with 0.26 at.% Ni
- 2022Methods—Spatially Resolved Diffraction Study of the Uniformity of a Li-Ion Pouch Cellcitations
- 2022Understanding efficient phosphorus-functionalization of graphite for vanadium flow batteries
- 2022Understanding efficient phosphorus-functionalization of graphite for vanadium flow batteriescitations
- 2021Garnet to hydrogarnet: effect of post synthesis treatment on cation substituted LLZO solid electrolyte and its effect on Li ion conductivitycitations
- 2021Polyoxometalate Modified Separator for Performance Enhancement of Magnesium–Sulfur Batteriescitations
- 2021$Co_{0.5}TiOPO_{4}@C$ as new negative electrode for sodium ion batteries: Synthesis, characterization, and elucidation of the electrochemical mechanism using in operando synchrotron diffractioncitations
- 2021Investigation of capacity fade for 18650-type lithium-ion batteries cycled in different state of charge (SoC) rangescitations
- 2020Choosing the right carbon additive is of vital importance for high-performance Sb-based Na-ion batteriescitations
- 2020Probing the Effect of Titanium Substitution on the Sodium Storage in Na₃Ni₂BiO₆ Honeycomb-Type Structurecitations
- 2020Amorphous Mo₅O₁₄-Type/Carbon Nanocomposite with Enhanced Electrochemical Capability for Lithium-Ion Batteries
- 2020Fatigue in High-Energy Commercial Li Batteries while Cycling at Standard Conditions:An in Situ Neutron Powder Diffraction Studycitations
- 2020Mechanochemical synthesis of amorphous and crystalline $Na_{2}P_{2}S_{6}$ – elucidation of local structural changes by X-ray total scattering and NMRcitations
- 2020Amorphous Mo 5 O 14 -Type/Carbon Nanocomposite with Enhanced Electrochemical Capability for Lithium-Ion Batteriescitations
- 2019Li20Mg6Cu13Al42: a new ordered quaternary superstructure to the icosahedral T-Mg32(Zn,Al)49 phase with fullerene-like Al60 clustercitations
- 2019Oxygen Activity in Li-Rich Disordered Rock-Salt Oxide and the Influence of $LiNbO_{3}$ Surface Modification on the Electrochemical Performancecitations
- 2019$Ni_{0.5}TiOPO_{4}$ phosphate: Sodium insertion mechanism and electrochemical performance in sodium-ion batteriescitations
- 2019$MnO_{2}$ and Reduced Graphene Oxide as Bifunctional Electrocatalysts for $Li–O_{2}$ Batteriescitations
- 2019Evidence of a Pseudo-Capacitive Behavior Combined with an Insertion/Extraction Reaction Upon Cycling of the Positive Electrode Material $mathrm{P2-Na_{x}Co_{0.9}Ti_{0.1}O_{2}}$ for Sodium-ion Batteriescitations
- 2019Amorphous versus Crystalline $Li_3PS_{4}$: Local Structural Changes during Synthesis and Li Ion Mobilitycitations
- 2018(De)Lithiation Mechanism of Hierarchically Layered LiNi$_{1/3}$Co$_{1/3}$Mn$_{1/3}$O$_{2}$ Cathodes during High-Voltage Cyclingcitations
- 2017Local Structures and Li Ion Dynamics in a $mathrm{Li_{10}SnP_{2}S_{12}}$ -Based Composite Observed by Multinuclear Solid-State NMR Spectroscopycitations
- 2017Average vs. local structure and composition-property phase diagram of $mathrm{K_{0.5}Na_{0.5}NbO_{3}-Bi_{½}Na_{½}TiO_{3}}$ systemcitations
- 2017LiBC<sub>3</sub>: a new borocarbide based on graphene and heterographene networkscitations
- 2017Average vs. local structure and composition-property phase diagram of K 0.5 Na 0.5 NbO 3 -Bi ½ Na ½ TiO 3 systemcitations
- 2016Lithium-air battery cathode modification via an unconventional thermal method employing boraxcitations
- 2016Surface properties and graphitization of polyacrylonitrile based fiber electrodes affecting the negative half-cell reaction in vanadium redox flow batteriescitations
- 2016The phase diagram of $mathrm{K_{0.5}Na_{0.5}NbO_{3}–Bi_{1/2}Na_{1/2}TiO_{3}}$citations
- 2016Effect of internal current flow during the sintering of zirconium diboride by field assisted sintering technology ; Effekt des internen Stromflusses während der Sinterung von ZrB2 by FAST/SPScitations
- 2016Structure and dielectric dispersion in cubic-like $mathrm{0.5K_{0.5}Na_{0.5}NbO_{3}-0.5Na_{1/2}Bi_{1/2}TiO_{3}}$ ceramiccitations
- 2014Carbon materials for the positive electrode in all-vanadium redox flow batteriescitations
- 2014Improving the rate capability of high voltage Lithium-ion battery cathode material $LiNi_{0.5}Mn_{1.5}O_{4}$ by ruthenium dopingcitations
- 2014Functionalised porous nanocomposites: a multidisciplinary approach to investigate designed structures for supercapacitor applicationscitations
- 2014High hydrogen content super-lightweight intermetallics from the Li–Mg–Si systemcitations
- 2014Improving the rate capability of high voltage Lithium-ion battery cathode material LiNi0.5Mn1.5O4 by ruthenium dopingcitations
- 2014Unusual oxidation behavior of light metal hydride by tetrahydrofuran solvent molecules confined in ordered mesoporous carboncitations
- 2014Unusual oxidation behavior of light metal hydride by tetrahydrofuran solvent molecules confined in ordered mesoporous carboncitations
- 2013Functionalised porous nanocompositescitations
- 2013Thermal stability of $Li_{1-Δ}M_{0.5}Mn_{1.5}O_{4}$ (M = Fe, Co, Ni) cathodes in different states of delithiation Δcitations
- 2011Ca3N2 and Mg3N2: Unpredicted High-Pressure Behavior of Binary Nitrides
- 2011Structure and dynamics of the fast lithium ion conductor "li 7La3Zr2O12"
- 2010Redetermination of iron dialuminide, FeAl2citations
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article
Understanding efficient phosphorus-functionalization of graphite for vanadium flow batteries
Abstract
Numerous surface treatment methods are known to enhance the electrochemical activity of graphite felt (GF), such as thermal activation or attachment of nanoparticulate catalysts. The integration of heteroatoms into the graphite lattice at the surface could be a promising technique for reliable and efficient electrode activation. However, these functionalization techniques are based on thermochemical activation, which makes it difficult to distinguish between activity effects other than foreign atom integration, such as defects and other surface groups that must be considered. In this work, we analyzed commercial and synthetic phosphorus-doped graphene and GF using different electrochemical and physicochemical techniques. Despite a high doping concentration, the activity of the commercial powder bonded to GF and coated on glassy carbon remained limited due to the low degree of graphitization and high oxygen content. Instead, a low phosphorus concentration of <1 at% combined with a high degree of graphitization increased the catalytic activity. Building on these findings, GF was rationally modified, resulting in twice the power density compared to the original material in full cell tests.