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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Jäppinen, Essi
VTT Technical Research Centre of Finland
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2021A comparative study of hydrazine alternatives in simulated steam generator conditions—Oxygen reaction kinetics and interaction with carbon steelcitations
- 2019Effect of lead and applied potential on corrosion of carbon steel in steam generator crevice solutionscitations
- 2017Effect of octadecylamine on carbon steel corrosion under PWR/VVER secondary side conditions
- 2017Effect of chloride transients on corrosion of low-alloyed steel under oxygenated high-temperature water conditions
- 2017Localized corrosion of pressure vessel steel in a boiling water reactor cladding flawcitations
- 2017Localized corrosion of pressure vessel steel in a boiling water reactor cladding flaw:Modeling of electrochemical conditions and dedicated experimentscitations
- 2017Corrosion Behavior of Carbon Steel Coated with Octadecylamine in the Secondary Circuit of a Pressurized Water Reactorcitations
- 2016Improving passivation of carbon steel in steam cycles of power plants with a film forming amine
- 2016Determining Zeta Potential of Magnetite Particles in PWR Secondary Side Water Treated with Ammonia or Ethanolamine by Using Streaming Potential Technique
- 2014The Effect of Temperature on the Zeta Potential of Magnetite Particles in Ammonia, Morpholine and Ethanolamine Solutions
Places of action
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article
A comparative study of hydrazine alternatives in simulated steam generator conditions—Oxygen reaction kinetics and interaction with carbon steel
Abstract
The efficiency of a range of hydrazine alternatives (carbohydrazide, diethyl-hydroxylamine, erythorbic acid and 2-butanone oxime) as oxygen scavengers and their interaction with carbon steel in simulated PWR steam generator inlet conditions are quantitatively compared. Kinetic parameters of oxygen reaction are estimated for the first time in such conditions using both an oxygen and a redox sensor. Electrochemical impedance measurements are performed to investigate the effect of studied alternatives on carbon steel corrosion. Using a quantitative interpretation of the impedance data by the Mixed-Conduction Model, the influence of hydrazine and its alternatives on charge transfer reactions at the oxide/solution interface and film growth/dissolution processes are discriminated. Conclusions are drawn on the comparative reaction rates of hydrazine alternatives with respect to oxygen consumption and steel passivation.