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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Wałęsa-Chorab, Monika
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Topics
Publications (11/11 displayed)
- 2023Influence of temperature on electrochemical and electrochromic properties of naphthalenediimide-triphenylamine-based polymercitations
- 2021Electropolymerization of [2 × 2] grid-type cobalt(II) complex with thiophene substituted dihydrazone ligandcitations
- 2020On-substrate postsynthetic metal ion exchange as a tool for tuning electrochromic properties of materialscitations
- 2019Complexation behavior of 6,6″-dimethyl-2,2′:6′,2″-terpyridine ligand with Co(II), Au(III), Ag(I), Zn(II) and Cd(II) ions: Synthesis, spectroscopic characterization and unusual structural motifscitations
- 2019Polymeric complexes of transition metal ions as electrochromic materials: Synthesis and propertiescitations
- 2019Synthesis and Characterization of Liquid-Crystalline Tetraoxapentacene Derivatives Exhibiting Aggregation-Induced Emissioncitations
- 2019Investigation of an electroactive immobilized azomethine for potential electrochromic usecitations
- 2018Coordination properties of N,N′-bis(5-methylsalicylidene)-2-hydroxy-1,3-propanediamine with d- and f-electron ions: crystal structure, stability in solution, spectroscopic and spectroelectrochemical studiescitations
- 2017Dipyrromethane functionalized monomers as precursors of electrochromic polymerscitations
- 2017The spectroscopic studies of new polymeric complexes of silver(I) and original mononuclear complexes of lanthanides(III) with benzimidazole-based hydrazonecitations
- 2013Mono-, di- and trinuclear complexes of bis(terpyridine) ligand: Synthesis, crystal structures and magnetic propertiescitations
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article
Electropolymerization of [2 × 2] grid-type cobalt(II) complex with thiophene substituted dihydrazone ligand
Abstract
The grid-type complex [Co4(L1-2H)4] containing dihydrazone ligand decorated with thiophene rings has been prepared. The complex undergoes oxidative electropolymerization onto ITO electrode to form purple thin film. The morphology of polymer film on ITO electrode was analyzed by SEM and AFM imagining. It was found that polymer obtained by electropolymerization method is homogenous and uniform. The obtained thin film exhibits color transition from purple via violet to blue due to the stepwise reduction of poly-[CoII4(L1-2H)4] into poly-[CoII2CoI2(L1-2H)4]2− and poly-[CoI4(L1-2H)4]4−. Its electrochromic properties such as long-term stability coloration efficiency and switching times have been investigated.