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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Kočí, Jan | Prague |
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| Azam, Siraj |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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Adams, Ralph W.
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Publications (7/7 displayed)
- 2024Rare earth mixed sandwich complexes with tetraalkylphospholide and cyclooctatetraenide ligandscitations
- 202331P Nuclear Magnetic Resonance Spectroscopy as a Probe of Thorium–Phosphorus Bond Covalency: Correlating Phosphorus Chemical Shift to Metal–Phosphorus Bond Ordercitations
- 2021Exceptional uranium(VI)-nitride triple bond covalency from 15 N nuclear magnetic resonance spectroscopy and quantum chemical analysis
- 2021Exceptional Uranium(VI)-Nitride Triple Bond Covalency from 15N Nuclear Magnetic Resonance Spectroscopy and Quantum Chemical Analysiscitations
- 2019Assembly and electrochemistry of carbon nanomaterials at the Liquid-liquid Interfacecitations
- 2018Understanding the Microstructure of Poly(p-phenylenevinylene)s Prepared by Ring Opening Metathesis Polymerization Using 13C-Labeled Paracyclophanediene Monomerscitations
- 2009Reversible Interactions with para-Hydrogen Enhance NMR Sensitivity by Polarization Transfercitations
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article
Assembly and electrochemistry of carbon nanomaterials at the Liquid-liquid Interface
Abstract
The interfacial adsorption of single-walled carbon nanotubes and few-layer graphene flakes, prepared by solution phase exfoliation, is compared. Strong adsorption of carbon nanotubes was observed at the water/1,2-dichloroethane interface, while a weaker adsorption of the graphene dispersion was seen. Addition of electrolyte to the organic phase was found to have a strong effect on the adsorption of graphene. A simple surface energy model does not fully explain these observations, rather residual charges and their distribution appears to be the key factor behind this difference in adsorptive behaviour. Carbon nanomaterials adsorbed at the liquid-liquid interface can function as bipolar electrodes: a preliminary investigation of the oxidation of the 1,2-dichlorobenzene by metal-modified graphene particles is performed.