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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ossowski, Tadeusz
University of Gdańsk
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2021Ultrasensitive electrochemical determination of the cancer biomarker protein sPD-L1 based on a BMS-8-modified gold electrodecitations
- 2021Adhesion as a component of retention force of overdenture prostheses-study on selected Au based dental materials used for telescopic crowns using atomic force microscopy and contact angle techniquescitations
- 2020Efficient method for the concentration determination of Fmoc groups incorporated in the core-shell materials by Fmoc-glycinecitations
- 2020Electrochemical performance of thin free-standing boron-doped diamond nanosheet electrodescitations
- 2020Dansyl-labelled Ag@SiO2 core-shell nanostructures-synthesis, characterization, and metal-enhanced fluorescencecitations
- 2019Understanding the origin of high corrosion inhibition efficiency of bee products towards aluminium alloys in alkaline environmentscitations
- 2018Optical monitoring of electrochemical processes with ITO-based lossy-mode resonance optical fiber sensor applied as an electrodecitations
- 2018Optical detection of ketoprofen by its electropolymerization on an indium tin oxide-coated optical fiber probecitations
- 2015Physicochemical properties of ternary oxovanadium(IV) complexes with oxydiacetate and 1,10-phenanthroline or 2,2'-bipyridine: cytoprotective activity in hippocampal neuronal HT22 cellscitations
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article
Understanding the origin of high corrosion inhibition efficiency of bee products towards aluminium alloys in alkaline environments
Abstract
Various bee products were found to be efficient corrosion inhibitors of aluminium in different environments. In particular, bee pollen was found to be highly effective in alkaline electrolytes, yet its highly complex composition and possible synergistic interactions hinder determination of the compounds acting as active corrosion inhibitors. The main purpose of the following work is to investigate the effect of solvents used for pollen extraction process on the corrosion inhibition of AA5754 alloy in alkaline environment. Both infrared and mass spectroscopies as well as chromatographic analysis were used to determine differences in the composition of each obtained extract.The inhibition efficiency (IE%) of each extract was determined by using the potentiodynamic polarization and impedance studies. The highest IE%, exceeding 90% at 10 gL-1, was recorded for the water/ethanol extract. Most importantly, it has been found that the dichloromethane extract containing less polar compounds enhanced the corrosion rate at low bee pollen concentrations, and offered lower inhibition efficiency at the concentrations above 10 gL-1. The adsorption isotherms were drawn based on dynamic impedance spectroscopy in galvanostatic mode (g-DEIS), while the measurements carried out at elevated temperatures allowed the construction of Arrhenius plots and, consequently, the confirmation of the physical mechanism of adsorption.