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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Le Hécho, Isabelle
Université de Pau et des Pays de l'Adour
in Cooperation with on an Cooperation-Score of 37%
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Publications (3/3 displayed)
- 2018Determination of the chromium(III) reduction mechanism during chromium electroplatingcitations
- 2018Determination of the chromium(III) reduction mechanism during chromium electroplatingcitations
- 2017Method for modifying a working electrode for a sensor detecting a metal dissolved in trace amounts in a liquid, electrode, sensor and use of same.
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article
Determination of the chromium(III) reduction mechanism during chromium electroplating
Abstract
The reduction mechanism of Cr (III) depends on the nature of the complexing agent present in electroplating solutions. In pure water solutions and without any other additives, Cr (III) is complexed with water molecules, creating a stable [Cr (H 2 O) 6] 3+ complex.[Cr (H 2 O) 6] 3+ can be reduced to Cr (0) in two steps via a chromium (II) intermediate species. However, this reduction is not quantitative, and the Cr (0) coating is difficult to grow. The destabilization of the [Cr (H 2 O) 6] 3+ complex via the addition of an organic complexing agent allows the …