People | Locations | Statistics |
---|---|---|
Naji, M. |
| |
Motta, Antonella |
| |
Aletan, Dirar |
| |
Mohamed, Tarek |
| |
Ertürk, Emre |
| |
Taccardi, Nicola |
| |
Kononenko, Denys |
| |
Petrov, R. H. | Madrid |
|
Alshaaer, Mazen | Brussels |
|
Bih, L. |
| |
Casati, R. |
| |
Muller, Hermance |
| |
Kočí, Jan | Prague |
|
Šuljagić, Marija |
| |
Kalteremidou, Kalliopi-Artemi | Brussels |
|
Azam, Siraj |
| |
Ospanova, Alyiya |
| |
Blanpain, Bart |
| |
Ali, M. A. |
| |
Popa, V. |
| |
Rančić, M. |
| |
Ollier, Nadège |
| |
Azevedo, Nuno Monteiro |
| |
Landes, Michael |
| |
Rignanese, Gian-Marco |
|
Santamaria, M.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (36/36 displayed)
- 2024Self-repairing Al2O3−TiO2 coatings fabricated through plasma electrolytic oxidation with various cathodic pulse parameters
- 2024Enhancing the PEEK composites-titanium interface performances through electrochemical treatment in fibre-metal laminates for aerospace applicationscitations
- 2024Process parameters and surface treatment effects on the mechanical and corrosion resistance properties of Ti6Al4V components produced by laser powder bed fusioncitations
- 2024Ni,Fe,Co-LDH Coated Porous Transport Layers for Zero-Gap Alkaline Water Electrolyzerscitations
- 2024Duplex plasma electrolytic oxidation/ hydroxyapatite- polydopamine coating on WE43 alloy for bone implants: Long-term corrosion resistance and biological propertiescitations
- 2024Surface treatments on 3D printed Ti6Al4V biomedical plates to enhance corrosion resistance in simulated physiological solutions and under inflammatory conditionscitations
- 2024Effect of citrate anion incorporation on dielectric properties of anodic oxide grown on Ti-Si alloycitations
- 2023Mono-, bi- and tri-metallic platinum group metal-free electrocatalysts for hydrogen evolution reaction following a facile synthetic routecitations
- 2023Enhancing corrosion resistance of anodized AA7075 alloys by electrodeposition of superhydrophobic coatingscitations
- 2023Highly Active and Stable NiCuMo Electrocatalyst Supported on 304 Stainless Steel Porous Transport Layer for Hydrogen Evolution in Alkaline Water Electrolyzercitations
- 2023Influence of anodizing surface treatment on the aging behavior in salt-fog environment of aluminum alloy 5083 to fiber reinforced composites adhesive jointscitations
- 2023A facile way to synthesize noble metal free TiO2 based catalysts for glycerol photoreformingcitations
- 2022The Effect of Electronic Properties of Anodized and Hard Anodized Ti and Ti6Al4V on Their Reactivity in Simulated Body Fluidcitations
- 2021One-step electrodeposition of superhydrophobic coating on 316L stainless steelcitations
- 2021Effects of anodizing surface treatment on the mechanical strength of aluminum alloy 5083 to fibre reinforced composites adhesive jointscitations
- 2021Tuning of the Mg Alloy AZ31 Anodizing Process for Biodegradable Implantscitations
- 2021Heterogeneous crystallization of zinc hydroxystannate on galvanized steel for enhancing the bond strength at the rebar/concrete interfacecitations
- 2020The effect of electrolytic solution composition on the structure, corrosion, and wear resistance of peo coatings on az31 magnesium alloycitations
- 2020Optimization of anodizing process of tantalum for Ta2O5-based capacitorscitations
- 2020Corrosion resistance of passive films on different stainless steel grades in food and beverage industrycitations
- 2020Fabrication of Bismuth Absorber Arrays for NTD-Ge Hard X-ray Microcalorimeterscitations
- 2019Dual Ni/Ni-Co electrodeposited coatings for improved erosion-corrosion behaviourcitations
- 2019Effect of pulse current mode on microstructure, composition and corrosion performance of the coatings produced by plasma electrolytic oxidation on AZ31 Mg alloycitations
- 2019Electroplated Ni/Ni-Co multilayer coatings for higher corrosion-erosion resistance
- 2019Electrochemical metallization ReRAMs (ECM) - Experiments and modelling: General discussioncitations
- 2019Synergistic effect of W incorporation and pulsed current mode on wear and tribocorrosion resistance of coatings grown by plasma electrolytic oxidation on 7075 Al alloycitations
- 2018A mathematical description accounting for the superfluous hydrogen evolution and the inductive behaviour observed during electrochemical measurements on magnesium.citations
- 2018Electroplated bismuth absorbers for planar NTD-Ge sensor arrays applied to hard x-ray detection in astrophysicscitations
- 2018Electronic properties and corrosion resistance of passive films on austenitic and duplex stainless steelscitations
- 2018Resistive switching of anodic TiO2-based Memristors
- 2018Band gap narrowing and dielectric constant enhancement of (NbxTa(1-x))2O5 by electrochemical nitrogen dopingcitations
- 2017Anodizing of aluminium and AA 2024-T3 alloy in chromic acid: effects of sulphate on film growthcitations
- 2017The amorphous semiconductor Schottky barrier approach to study the electronic properties of anodic films on Ticitations
- 2015Behavior of alloying elements during anodizing of Mg-Cu and Mg-W alloys in a fluoride/glycerol electrolytecitations
- 2015Behavior of alloying elements during anodizing of Mg-Cu and Mg-W alloys in a fluoride/glycerol electrolytecitations
- 2012Growth and field crystallization of anodic films on Ta–Nb alloyscitations
Places of action
Organizations | Location | People |
---|
article
A mathematical description accounting for the superfluous hydrogen evolution and the inductive behaviour observed during electrochemical measurements on magnesium.
Abstract
When electrochemical techniques are used to probe the surface of corroding magnesium with the aim of obtaining quantitative information on the corrosion process, two peculiarities are generally observed: i) with anodic polarization, the rate of hydrogen evolution increases instead of decreasing and ii) during electrochemical impedance spectroscopy measurements, an inductive contribution is often observed at the low-frequency end of the spectra. The presence of these two phenomena clearly has an impact on the methodology that should be applied to correctly estimate corrosion rates from electrochemical data. The aim of this work is to provide a general mathematical description of the corroding magnesium surface that, under minimal a priori assumptions regarding the reaction kinetics,can account simultaneously for both superfluous hydrogen evolution and inductive response.The mathematical results are consistent with the suggestion that the superfluous hydrogen evolution is mainly related to the increase of the surface of the active corrosion front during anodic polarization. Further, the obtained results show that the inductive response is expected when, at the corrosion front, oxidation of magnesium proceeds faster than hydrogen evolution.