| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Curioni, Michele
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (33/33 displayed)
- 2024Evaluating organic coating performance by EIS: Correlation between long-term EIS measurements and corrosion of the metal substratecitations
- 2023Mitigation effects of over-aging (T73) induced intergranular corrosion on stress corrosion cracking of AA7075 aluminum alloy and behaviors of η phase grain boundary precipitates during the intergranular corrosion formationcitations
- 2022The influence of mechanical grinding on the microstructure and corrosion behaviour of A356 aluminium alloyscitations
- 2021The influence of mechanical grinding on the microstructure and corrosion behaviour of A356 aluminium alloys
- 2021Relationship between natural exposure testing and cyclic corrosion testing ISO 20340 for the assessment of the durability of powder-coated steelcitations
- 2021Multiscale analysis of grain boundary microstructure in high strength 7xxx Al alloyscitations
- 2020The effect of exposure conditions on performance evaluation of post-treated anodic oxides on an aerospace aluminium alloy: comparison between salt spray and immersion testing.
- 2020Thermodynamic Equivalence Charts for Stress Corrosion Cracking Studies in Hydrogenated Steam, High Pressure and Supercritical Watercitations
- 2020Thermodynamic Equivalence Charts for Stress Corrosion Cracking Studies in Hydrogenated Steam, High Pressure and Supercritical Watercitations
- 2020Exploring the Use of an AC-DC-AC Technique for the Evaluation of Anticorrosion Performance of Anodic Films on Aluminium Alloyscitations
- 2020Investigating the effect of pH on corroding magnesium by dynamic pH sweep coupled with electrochemical measurements
- 2020Investigating the effect of pH on corroding magnesium by dynamic pH sweep coupled with electrochemical measurements
- 2020Corrosion Testing of Anodized Aerospace Alloys: Comparison between Immersion and Salt Spray Testing using Electrochemical Impedance Spectroscopycitations
- 2019Incorporation of alloying elements into porous anodic films on aluminium alloys: the role of cell diametercitations
- 2018Relationship Between the Inductive Response Observed During Electrochemical Impedance Measurements on Aluminium and Local Corrosion Processescitations
- 2018Effects of oxygen evolution on the voltage and film morphology during galvanostatic anodizing of AA 2024-T3 aluminium alloy in sulphuric acid at -2 and 24 °C.citations
- 2018A mathematical description accounting for the superfluous hydrogen evolution and the inductive behaviour observed during electrochemical measurements on magnesium.citations
- 2018Complete long-term corrosion protection with chemical vapor deposited graphenecitations
- 2018Effect of anodizing conditions on the cell morphology of anodic films on AA2024-T3 alloycitations
- 2018Effect of fluorozirconic acid on anodizing of aluminium and AA 2024-T3 alloy in sulphuric and tartaric-sulphuric acidscitations
- 2017Electrochemical and Microstructural Characterization of Alloy 600 in Low Pressure H2-steam
- 2017Electrochemical and Microstructural Characterization of Alloy 600 in Low Pressure H2-steam
- 2017Effects of fluoride ions in the growth of barrier-type films on aluminiumcitations
- 2017Gravimetric measurement of oxygen evolution during anodizing of aluminium alloyscitations
- 2017The contribution of hydrogen evolution processes during corrosion of aluminium and aluminium alloys investigated by potentiodynamic polarisation coupled with real-time hydrogen measurementcitations
- 2016Study of the Linear Friction Welding Process of Dissimilar Ti-6Al-4V–Stainless Steel Jointscitations
- 2016Application of EIS to In Situ Characterization of Hydrothermal Sealing of Anodized Aluminum Alloys: Comparison between Hexavalent Chromium-Based Sealing, Hot Water Sealing and Cerium-Based Sealingcitations
- 2015Protective Film Formation on AA2024-T3 Aluminum Alloy by Leaching of Lithium Carbonate from an Organic Coating
- 2014Electrochemical characteristics of a carbon fibre composite and the associated galvanic effects with aluminium alloyscitations
- 2014Development of Cerium-Rich Layers on Anodic Films Formed on Pure Aluminium and AA7075 T6 Alloycitations
- 2014Electrochemical characteristics of a carbon fibre composite and theassociated galvanic effects with aluminium alloys
- 2013Revealing the three dimensional internal structure of aluminium alloyscitations
- 2013Galvanic corrosion between magnesium alloys and steelcitations
Places of action
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article
A mathematical description accounting for the superfluous hydrogen evolution and the inductive behaviour observed during electrochemical measurements on magnesium.
Abstract
When electrochemical techniques are used to probe the surface of corroding magnesium with the aim of obtaining quantitative information on the corrosion process, two peculiarities are generally observed: i) with anodic polarization, the rate of hydrogen evolution increases instead of decreasing and ii) during electrochemical impedance spectroscopy measurements, an inductive contribution is often observed at the low-frequency end of the spectra. The presence of these two phenomena clearly has an impact on the methodology that should be applied to correctly estimate corrosion rates from electrochemical data. The aim of this work is to provide a general mathematical description of the corroding magnesium surface that, under minimal a priori assumptions regarding the reaction kinetics,can account simultaneously for both superfluous hydrogen evolution and inductive response.The mathematical results are consistent with the suggestion that the superfluous hydrogen evolution is mainly related to the increase of the surface of the active corrosion front during anodic polarization. Further, the obtained results show that the inductive response is expected when, at the corrosion front, oxidation of magnesium proceeds faster than hydrogen evolution.