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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Patroniak, Violetta
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Self-assembly of simple Schiff base ligand into unique saddle-type [4x4] tetranuclear architecture and its application as selective voltammetric dopamine sensor in aqueous conditionscitations
- 2023New N4-Donor Ligands as Supramolecular Guests for DNA and RNA: Synthesis, Structural Characterization, In Silico, Spectrophotometric and Antimicrobial Studiescitations
- 2021Electropolymerization of [2 × 2] grid-type cobalt(II) complex with thiophene substituted dihydrazone ligandcitations
- 2020Graphene oxide-mesoporous SiO2 hybrid composite for fast and efficient removal of organic cationic contaminantscitations
- 2020Complex-decorated surfactant-encapsulated clusters (CD-SECs) as novel multidynamic hybrid materialscitations
- 2019Complexation behavior of 6,6″-dimethyl-2,2′:6′,2″-terpyridine ligand with Co(II), Au(III), Ag(I), Zn(II) and Cd(II) ions: Synthesis, spectroscopic characterization and unusual structural motifscitations
- 2019High‐Performance Graphene‐Based Cementitious Compositescitations
- 2018Graphene oxide-branched polyethylenimine foams for efficient removal of toxic cations from watercitations
- 2017Dipyrromethane functionalized monomers as precursors of electrochromic polymerscitations
- 2017The spectroscopic studies of new polymeric complexes of silver(I) and original mononuclear complexes of lanthanides(III) with benzimidazole-based hydrazonecitations
- 2016Utilization of a new gold/Schiff-base iron(iii) complex composite as a highly sensitive voltammetric sensor for determination of epinephrine in the presence of ascorbic acidcitations
- 2013Mono-, di- and trinuclear complexes of bis(terpyridine) ligand: Synthesis, crystal structures and magnetic propertiescitations
Places of action
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article
Dipyrromethane functionalized monomers as precursors of electrochromic polymers
Abstract
Dipyrromethane functionalized monomers 1–4 have been synthesized and characterized using spectroscopic methods and X-ray diffraction analysis (monomer 4 and dialdehydes 5 and 6). Monomers exhibit irreversible electrochemical oxidation but during multiple oxidation cycles electropolymerization of monomers on the electrode surface occurs. Electrochemical polymerization of monomers were carried out in acetonitrile solution using tetrabutylammonium hexafluorophosphate (TBAPF<sub>6</sub>) as a supporting electrolyte. It was found that faster electropolymerization occurs when monomer contains more than one dipyrromethane unit and obtained polymers have better stability. The morphology of polymer films on ITO electrodes was analyzed by SEM and AFM techniques. It was found that polymers obtained by electropolymerization method are homogenous and uniform with low roughness, RMS value: 105 Å and 153 Å for poly-1 and poly-2 respectively. Obtained thin films of polymers poly-1 and poly-2 exhibit interesting optical properties dependent on the core of monomer and were used as active layers for the construction of electrochromic devices. The colors of oxidized states of electrochromic polymers can be easily modified by the change of electroactive cores in monomers.</p>