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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Forsyth, M.
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Publications (8/8 displayed)
- 2017Properties of High Na-Ion Content N-Propyl-N-Methylpyrrolidinium Bis(Fluorosulfonyl)Imide -Ethylene Carbonate Electrolytescitations
- 2016Inorganic-organic ionic liquid electrolytes enabling high energy-density metal electrodes for energy storagecitations
- 2016Recent developments in environment-friendly corrosion inhibitors for mild steel
- 2012Electrochemical etching of aluminium alloy in ionic liquids
- 2011Anodising AA5083 aluminium alloy using ionic liquids
- 2011Anodic oxidation of AZ31 Mg alloy in ionic liquid
- 2003Cerium acetylacetonates—new aspects, including the lamellar clathrate [Ce(acac)4]·10H2Ocitations
- 2001The synthesis of high molecular weight polybutene-1 catalyzed by Cp*Ti(OBz)3/MAO
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article
Properties of High Na-Ion Content N-Propyl-N-Methylpyrrolidinium Bis(Fluorosulfonyl)Imide -Ethylene Carbonate Electrolytes
Abstract
<p>Sodium-based batteries have emerged as promising alternatives to Li-based batteries for future safe, high energy-density energy storage. They are expected to be cheaper, due to the greater abundance of Na and likely reduction in raw material costs. In this study, we investigate the properties of superconcentrated sodium bis(fluorosulfonyl)amide (NaFSI) mixtures with the ionic liquid (IL) methylpropylpyrrolinium (C<sub>3</sub>mpyr) FSI in the presence of ethylene carbonate (EC) in the liquid and gel states. Ionic conductivity and thermal stability are evaluated through electrochemical impedance spectroscopy (EIS) and differential scanning calorimetry (DSC), respectively. NaFSI is soluble in the IL up to 55 mol% Na; adding EC (30 wt.%) to the IL almost doubles the ionic conductivity at ambient temperature. The temperature dependence of conductivity is well described by the Vogel-Tamman-Fulcher equation. NMR spectroscopy and Pulse Field Gradient NMR diffusion were employed to investigate transport in these electrolyte systems, while the chemical interactions were also studied using ATR-FTIR. Stable plasticized gel electrolytes were observed, even at 30 wt. % EC; the formation of the gel does not significantly affect the liquid-like ion dynamics in these materials, as shown by DSC and FTIR analysis. The Na<sup>+</sup> transference number of Na<sub>0</sub>.<sub>55</sub>[C<sub>3</sub>mpyr]<sub>0.45</sub>[FSI] + 30 wt.% EC was up to 0.32, and deposition and dissolution of sodium metal were observed in cyclic voltammetry around 0 V vs. Na/Na<sup>+</sup>. Moreover, the suitability of the prepared electrolyte is preliminarily verified in half-cells at room temperature using Na<sub>3</sub>V<sub>2</sub>(PO<sub>4</sub>)<sub>3</sub> as a cathode. The cells delivered capacity of 52.4 mAhg<sup>−1</sup> at C/20.</p>