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Publications (4/4 displayed)
- 2017Facile and green reduction of graphene oxide by a reduced polyoxometalate and formation of a nanohybridcitations
- 2017Improved EIS Analysis of the Electrochemical Behaviour of Carbon Steel in Alkaline Solutioncitations
- 2016New insights into the cathodic dissolution of aluminium using electrochemical methodscitations
- 2013Incongruent dissolution of copper in an Al-Cu assembling. Influence of local pH changescitations
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article
Improved EIS Analysis of the Electrochemical Behaviour of Carbon Steel in Alkaline Solution
Abstract
Steady-state polarization curves, X-ray photoelectron spectroscopy, and impedance spectroscopy were used to explore the electrochemical properties for carbon steel in alkaline electrolytes. The complex-capacitance representation allowed determination of a capacitance value at high frequency, from which the oxide film thickness could be estimated. These results are in good agreement with values obtained using the power-law model, providing a single mathematical model that is shown to apply in both the anodic and cathodic domains for the characterization of an oxide layer.