| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Worrall, Stephen D.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2024Block copolymer synthesis in ionic liquid via polymerisation-induced self-assembly: A convenient route to gel electrolytescitations
- 2018Anodic dissolution growth of metal-organic framework HKUST-1 monitored:Via in situ electrochemical atomic force microscopy
- 2018Anodic dissolution growth of metal-organic framework HKUST-1 monitored via in situ electrochemical atomic force microscopycitations
- 2018Anodic dissolution growth of metal-organic framework HKUST-1 monitored via in situ electrochemical atomic force microscopycitations
- 2017Electronic structure design for nanoporous, electrically conductive zeolitic imidazolate frameworks
- 2017Electronic structure design for nanoporous, electrically conductive zeolitic imidazolate frameworkscitations
- 2017Electronic structure design for nanoporous, electrically conductive zeolitic imidazolate frameworkscitations
- 2017Hydrogen Evolution at Liquid|Liquid Interfaces Catalysed by 2D Materialscitations
- 2017Hydrogen evolution and capacitance behavior of Au/Pd nanoparticle-decorated graphene heterostructurescitations
- 2016Metal-organic framework templated electrodeposition of functional gold nanostructurescitations
Places of action
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article
Metal-organic framework templated electrodeposition of functional gold nanostructures
Abstract
Utilizing a pair of quick, scalable electrochemical processes, the permanently porous MOF HKUST-1 was electrochemically grown on a copper electrode and this HKUST-1-coated electrode was used to template electrodeposition of a gold nanostructure within the pore network of the MOF. Transmission electron microscopy demonstrates that a proportion of the gold nanostructures exhibit structural features replicating the pore space of this ~1.4 nm maximum pore diameter MOF, as well as regions that are larger in size. Scanning electron microscopy shows that the electrodeposited gold nanostructure, produced under certain conditions of synthesis and template removal, is sufficiently inter-grown and mechanically robust to retain the octahedral morphology of the HKUST-1 template crystals. The functionality of the gold nanostructure within the crystalline HKUST-1 was demonstrated through the surface enhanced Raman spectroscopic (SERS) detection of 4-fluorothiophenol at concentrations as low as 1 µM. The reported process is confirmed as a viable electrodeposition method for obtaining functional, accessible metal nanostructures encapsulated within MOF crystals.