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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bissett, Mark A.
University of Manchester
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2024Synergistic Improvement in the Thermal Conductivity of Hybrid Boron Nitride Nanotube/Nanosheet Epoxy Compositescitations
- 2024High-performance hybrid glass fibre epoxy composites reinforced with amine functionalised graphene oxide for structural applicationscitations
- 2024Structural Health Monitoring of Scarf Bonded Repaired Glass/Epoxy Laminates Interleaved with Carbon Non-woven Veilcitations
- 2023Tribology of Copper Metal Matrix Composites Reinforced with Fluorinated Graphene Oxide Nanosheets: Implications for Solid Lubricants in Mechanical Switchescitations
- 2023Novel techniques for characterising graphene nanoplatelets using Raman spectroscopy and machine learningcitations
- 2022Joule heating and mechanical properties of epoxy/graphene based aerogel compositecitations
- 2021Effect of graphene nanoplatelets on the mechanical and gas barrier properties of woven carbon fibre/epoxy compositescitations
- 2021Fabrication and Mechanical Performance of Graphene Nanoplatelet/Glass Fiber Reinforced Polymer Hybrid Composites
- 2020Sustainable, high barrier polyaleuritate/nanocellulose biocompositescitations
- 2020Multifunctional Biocomposites Based on Polyhydroxyalkanoate and Graphene/Carbon Nanofiber Hybrids for Electrical and Thermal Applicationscitations
- 2018Anodic dissolution growth of metal-organic framework HKUST-1 monitored:Via in situ electrochemical atomic force microscopy
- 2018Anodic dissolution growth of metal-organic framework HKUST-1 monitored via in situ electrochemical atomic force microscopycitations
- 2018Anodic dissolution growth of metal-organic framework HKUST-1 monitored via in situ electrochemical atomic force microscopycitations
- 2017Hydrogen Evolution at Liquid|Liquid Interfaces Catalysed by 2D Materialscitations
- 2016Metal-organic framework templated electrodeposition of functional gold nanostructurescitations
- 2016Asymmetric MoS2-graphene-metal sandwiches: Preparation, characterization and applicationcitations
- 2015Tunable doping of graphene nanoribbon arrays by chemical functionalizationcitations
- 2015Synthesis of Lateral Size-Controlled Monolayer 1H-MoS2@Oleylamine as Supercapacitor Electrodes.citations
- 2012Effect of domain boundaries on the Raman spectra of mechanically strained graphenecitations
- 2011Transition from single to multi-walled carbon nanotubes grown by inductively coupled plasma enhanced chemical vapor depositioncitations
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article
Metal-organic framework templated electrodeposition of functional gold nanostructures
Abstract
Utilizing a pair of quick, scalable electrochemical processes, the permanently porous MOF HKUST-1 was electrochemically grown on a copper electrode and this HKUST-1-coated electrode was used to template electrodeposition of a gold nanostructure within the pore network of the MOF. Transmission electron microscopy demonstrates that a proportion of the gold nanostructures exhibit structural features replicating the pore space of this ~1.4 nm maximum pore diameter MOF, as well as regions that are larger in size. Scanning electron microscopy shows that the electrodeposited gold nanostructure, produced under certain conditions of synthesis and template removal, is sufficiently inter-grown and mechanically robust to retain the octahedral morphology of the HKUST-1 template crystals. The functionality of the gold nanostructure within the crystalline HKUST-1 was demonstrated through the surface enhanced Raman spectroscopic (SERS) detection of 4-fluorothiophenol at concentrations as low as 1 µM. The reported process is confirmed as a viable electrodeposition method for obtaining functional, accessible metal nanostructures encapsulated within MOF crystals.