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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Afzal, Muhammad
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Publications (5/5 displayed)
- 2022Mechanical and Durability Evaluation of Metakaolin as Cement Replacement Material in Concretecitations
- 2019Semiconductor-ionic Materials for Low Temperature Solid Oxide Fuel Cells
- 2019 Gasification reactivity and synergistic effect of conventional and microwave pyrolysis derived algae chars in CO 2 atmosphere citations
- 2018Optimizing Cold Compression Deformation to Remove Residual Stresses in Die Forged Disc of Al-Mg-Si Alloycitations
- 2015Synthesis of Ba0.3Ca0.7Co0.8Fe0.2O3-δ composite material as novel catalytic cathode for ceria-carbonate electrolyte fuel cellscitations
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article
Synthesis of Ba0.3Ca0.7Co0.8Fe0.2O3-δ composite material as novel catalytic cathode for ceria-carbonate electrolyte fuel cells
Abstract
This work reports a new composite BaxCa1-xCoyFe1-yO3-δ (BCCF) cathode material for advanced and low temperature solid oxide fuel cells (SOFCs). The BCCF-based composite material was synthesized by sol gel method and investigated as a catalytic cathode for low temperature (LT) SOFCs. XRD analysis of the as-prepared material revealed the dominating BCCF perovskite structure as the main phase accompanied with cobalt and calcium oxides as the secondary phases resulting into an overall composite structure. Structure and morphology of the sample was observed by Field Emission Scanning Electron Microscope (FE-SEM). In particular, the Ba0.3Ca0.7Co0.8Fe0.2O3-δ (BCCF37) showed a maximum conductivity of 143 S cm−1 in air at 550 °C measured by DC 4 probe method. The BCCF at the optimized composition exhibited much higher electrical conductivities than the commercial Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF) perovskite cathode material. A maximum power density of 325 mW cm−2 at 550 °C is achieved for the ceria-carbonate electrolyte fuel cell with BCCF37 as the cathode material.