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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Kočí, Jan | Prague |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Ali, M. A. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Chapman, Robert S. L.
Charles River Laboratories (United Kingdom)
in Cooperation with on an Cooperation-Score of 37%
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article
Electrocatalytic carbohydrate oxidation with 4-benzoyloxy-TEMPO heterogenised in a polymer of intrinsic microporosity
Abstract
The enzymeless and operationally simple electrocatalytic oxidation of carbohydrates by "heterogenised" 4-benzoyloxy-TEMPO either (i) immobilised as microcrystals at a glassy carbon electrode surface or (ii) embedded into a polymer of intrinsic microporosity (PIM-EA-TB with 1027 m 2 g -1 BET surface area and highly rigid framework structure) has been studied in aqueous phosphate buffer of pH 12. It is shown that in contrast to microcrystal deposits, 4-benzolyoxy-TEMPO co-immobilised within PIM-EA-TB give stable catalytic responses for both, stationary and rotating disc electrode systems and for oxidation of glucose, sorbitol, and sucrose. The rigidity and intrinsic microporosity of PIM-EA-TB allow (slow) substrate and product diffusion, whilst maintaining 4-benzoyloxy-TEMPO immobilised in active molecular form.