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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Hjelm, Johan
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (37/37 displayed)
- 2024Unifying the ORR and OER with surface oxygen and extracting their intrinsic activities on platinumcitations
- 2023Tuning Polybenzimidazole-Derived Crosslinked Interpenetrating Network Membranes for Vanadium Redox Flow Batteriescitations
- 2023Tuning Polybenzimidazole-Derived Crosslinked Interpenetrating Network Membranes for Vanadium Redox Flow Batteriescitations
- 2022Leveraging coordination chemistry in the design of bipolar energy storage materials for redox flow batteriescitations
- 2022Leveraging coordination chemistry in the design of bipolar energy storage materials for redox flow batteriescitations
- 2018Noise Phenomena in Electrochemical Impedance Spectroscopy of Polymer Electrolyte Membrane Electrolysis Cellscitations
- 2018Reactivating the Ni-YSZ electrode in solid oxide cells and stacks by infiltrationcitations
- 2017A Physically-Based Equivalent Circuit Model for the Impedance of a LiFePO 4 /Graphite 26650 Cylindrical Cellcitations
- 2017Electrochemical Characterization of a PEMEC Using Impedance Spectroscopycitations
- 2017Carbon deposition and sulfur poisoning during CO 2 electrolysis in nickel-based solid oxide cell electrodescitations
- 2017A Physically-Based Equivalent Circuit Model for the Impedance of a LiFePO4/Graphite 26650 Cylindrical Cellcitations
- 2017Carbon deposition and sulfur poisoning during CO2 electrolysis in nickel-based solid oxide cell electrodescitations
- 2017Chemical and Electrochemical Properties of La0.58Sr0.4Fe0.8Co0.2O3-δ (LSCF) Thin Films upon Oxygen Reduction and Evolution Reactions
- 2016Electron microscopy investigations of changes in morphology and conductivity of LiFePO4/C electrodescitations
- 2016Electrochemical Characterization of PEMECs Operating at Various Current Densities
- 2016Quantitative review of degradation and lifetime of solid oxide cells and stacks
- 2016Electron microscopy investigations of changes in morphology and conductivity of LiFePO 4 /C electrodescitations
- 2015Carbon Deposition during CO2 Electrolysis in Ni-Based Solid-Oxide-Cell Electrodes
- 2015Carbon Deposition during CO2 Electrolysis in Ni-Based Solid-Oxide-Cell Electrodes
- 2015Kinetic Studies on Ni-YSZ Composite Electrodescitations
- 2014Structural instability and electrical properties in epitaxial Er 2 O 3 -stabilized Bi 2 O 3 thin filmscitations
- 2014Degradation Studies on LiFePO 4 cathode
- 2014Degradation Studies on LiFePO4 cathode
- 2014Impedance of SOFC electrodes: A review and a comprehensive case study on the impedance of LSM:YSZ cathodescitations
- 2014Structural instability and electrical properties in epitaxial Er2O3-stabilized Bi2O3 thin filmscitations
- 2012Durable and Robust Solid Oxide Fuel Cells
- 2012Highly durable anode supported solid oxide fuel cell with an infiltrated cathodecitations
- 2011Manufacturing and characterization of metal-supported solid oxide fuel cellscitations
- 2011Manufacturing and characterization of metal-supported solid oxide fuel cellscitations
- 2011Planar metal-supported SOFC with novel cermet anodecitations
- 2011Planar metal-supported SOFC with novel cermet anodecitations
- 2011A high performance ceria based interdiffusion barrier layer prepared by spin-coatingcitations
- 2009Development of Planar Metal Supported SOFC with Novel Cermet Anodecitations
- 2009Development of Planar Metal Supported SOFC with Novel Cermet Anodecitations
- 2008Photochromism and electrochemistry of a dithienylcyclopentene electroactive polymercitations
- 2008Photochromism and electrochemistry of a dithienylcyclopentene electroactive polymercitations
- 2007Electrochemical Impedance Studies of SOFC Cathodescitations
Places of action
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article
Impedance of SOFC electrodes: A review and a comprehensive case study on the impedance of LSM:YSZ cathodes
Abstract
It was shown through a comprehensive impedance spectroscopy study that the impedance of the classic composite LSM:YSZ (lanthanum strontium manganite and yttria stabilized zirconia) solid oxide fuel cell (SOFC) cathode can be described well with porous electrode theory. Furthermore, it was illustrated through a literature review on SOFC electrodes that porous electrode theory not only describes the classic LSM:YSZ SOFC cathode well, but SOFC electrodes in general. The extensive impedance spectroscopy study of LSM:YSZ cathodes consisted of measurements on cathodes with three different sintering temperatures and hence different microstructures and varying degrees of LSM/YSZ solid state interactions. LSM based composite cathodes, where YSZ was replaced with CGO was also studied in order to acquire further knowledge on the chemical compatibility between LSM and YSZ. All impedance measurements were acquired in the very broad temperature range of 200–900°C for complete elucidation of the impedance. All impedance spectra were analyzed in terms of porous electrode theory. Physical materials parameters were extracted from the analysis, which were in excellent accordance with literature values. Valuable insight about the dissolution of Mn in the cathode composite material YSZ during preparation was furthermore provided along with valuable engineering characteristics such as the electrochemical utilization thickness. From the combined impedance study and literature review, it is clear, that porous electrode theory is the most suitable framework for any type of porous composite SOFC electrode evaluation.