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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Jensen, Pernille Erland
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2024Oxidation of sulfides from secondary materials in cementitious binders as a function of environmental conditions
- 2024Electrodialytic extraction of copper, lead and zinc from sulfide mine tailings:Optimization of current density and operation time
- 2021Screening for key material parameters affecting early-age and mechanical properties of blended cementitious binders with mine tailingscitations
- 2019Evaluation of mine tailings’ potential as supplementary cementitious materials based on chemical, mineralogical and physical characteristicscitations
- 2017The influence of sediment properties and experimental variables on the efficiency of electrodialytic removal of metals from sedimentcitations
- 2016Degradation of oil products in a soil from a Russian Barents hot-spot during electrodialytic remediationcitations
- 2016Wood ash used as partly sand and/or cement replacement in mortarcitations
- 2016Replacement of 5% of OPC by fly ash and APC residues from MSWI with electrodialytic pre-treatment
- 2015Comparison of 2-compartment, 3-compartment and stack designs for electrodialytic removal of heavy metals from harbour sedimentscitations
- 2015Screening of variable importance for optimizing electrodialytic remediation of heavy metals from polluted harbour sedimentscitations
- 2015Multivariate methods for evaluating the efficiency of electrodialytic removal of heavy metals from polluted harbour sedimentscitations
- 2014Electrodialytically treated MSWI APC residue as substitute for cement in mortar
- 2013Effect of pulse current on acidification and removal of Cu, Cd, and As during suspended electrodialytic soil remediationcitations
- 2012Electrodialytic remediation of suspended soil – Comparison of two different soil fractionscitations
- 2007Electrodialytic extraction of Cd and Cu from sediment from Sisimiut Harbour, Greenlandcitations
Places of action
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article
Effect of pulse current on acidification and removal of Cu, Cd, and As during suspended electrodialytic soil remediation
Abstract
<p>The effect of pulse current on the acidification process and the removal of heavy metals during suspended electrodialytic soil remediation were investigated in this work. Eight experiments with constant and pulse current in two polluted soils were conducted using a 3-compartment membrane cell, predominately working under overlimiting current density conditions. Soil 1 was sampled from a pile of excavated soil at a site with mixed industrial pollution (Cu and Cd), and soil 2 was sampled from the top layer of a wood preservation site (Cu and As). Results showed that pulse current improved the acidification by supplying more reactive H<sup>+ </sup>ions (defined as the H<sup>+</sup> ions causing release of heavy metals from soil particles). The molar ratio of reactive H<sup>+</sup> ions to total produced H<sup>+</sup> ions (<em>R</em><sub>H+</sub>/<em>P</em><sub>H+</sub>) was higher in every pulse current experiment than in the corresponding constant current experiment. In addition the removal efficiencies of heavy metals were also improved. The carbonate buffering system in a soil is the first mechanism reacting with the produced H<sup>+</sup> ions and impeding the heavy metal mobilization. It was found that the effect of improvement on both the acidification process and the removal of heavy metals were more significant in the soil with highest buffering capacity than the soil with low. Energy distribution analysis demonstrated that most energy was consumed by the transport of ionic species through the soil suspension, and then followed by membranes and electrolytes. The pulse current decreased the energy consumption to different extent depending on the pulse frequency. The lowest energy consumption was obtained in the experiment with the highest pulse frequency (96 cycles per day) for both soils.</p>