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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Rasul, Shahid
Northumbria University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2024Shaping sustainable pathwayscitations
- 2024Enhancing lithium-ion battery anode performance via heterogeneous nucleation of silver within Ti3C2-MXene frameworkscitations
- 2024Innovative Tin and hard carbon architecture for enhanced stability in lithium-ion battery anodescitations
- 2024Sputtered Hard Carbon for High-Performance Energy Storage Batteries
- 2024Designing Molybdenum Trioxide and Hard Carbon Architecture for Stable Lithium‐Ion Battery Anodescitations
- 2023Multi-layered Sn and Hard Carbon Architectures for Long-Term Stability and High-Capacity Lithium-Ion Battery Anodes
- 2023Fabrication of WO3 / Fe 2 O 3 heterostructure photoanode by PVD for photoelectrochemical applicationscitations
- 2023Advancing Lithium-Ion Battery Anodes: Novel Sn and Hard Carbon Architectures for Long-Term Stability and High Capacity
- 2023Molybdenum Incorporated O3‐type Sodium Layered Oxide Cathodes for High‐Performance Sodium‐Ion Batteriescitations
- 2022Coal fly ash supported CoFe2O4 nanocompositescitations
- 2021Enhancement of mechanical and corrosion resistance properties of electrodeposited Ni–P–TiC composite coatingscitations
- 2021In Situ Printing and Functionalization of Hybrid Polymer-Ceramic Composites Using a Commercial 3D Printer and Dielectrophoresis—A Novel Conceptual Designcitations
- 2021In situ printing and functionalization of hybrid polymer-ceramic composites using a commercial 3d printer and dielectrophoresis—a novel conceptual designcitations
- 2016Characterization of a porous carbon material functionalized with cobalt-oxide/cobalt core-shell nanoparticles for lithium ion battery electrodes
- 2016A simple UV-ozone surface treatment to enhance photocatalytic performance of TiO 2 loaded polymer nanofiber membranescitations
- 2014Photoelectrochemical and electrocatalytic properties of thermally oxidized copper oxide for efficient solar fuel productioncitations
- 2012High capacity positive electrodes for secondary Mg-ion batteriescitations
- 2012Synthesis and electrochemical behavior of hollandite MnO2/acetylene black composite cathode for secondary Mg-ion batteriescitations
Places of action
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article
High capacity positive electrodes for secondary Mg-ion batteries
Abstract
<p>Composites of layered structured Birnessite-MnO <sub>2</sub> and tunnel structured Hollandite-MnO <sub>2</sub> in presence of acetylene black were synthesized as positive electrode materials for rechargeable Mg-ion batteries. Reversible insertion/extraction of Mg-ion in the host structures was examined in the potential range of -1.8 to 1.0 V vs. Ag/Ag <sup>+</sup>. Results indicated that Mg-ion exchanged Birnessite/acetylene black composite showed the highest discharge capacity (109 mAh g <sup>-1</sup>) at 1st discharge, when compared to other microstructures of Birnessite. Meanwhile, the composite comprising of 65 wt% Hol-MnO <sub>2</sub> and 35 wt% acetylene black showed very high insertion of Mg-ion (0.87 Mg/Mn) corresponding to discharge capacity of 475 mAh g <sup>-1</sup> when tested at 60°C in galvanostatic mode. The layered and tunneled framework of the MnO <sub>2</sub> was retained with minor displacive adjustments even after substantial Mg-ion insertion/extraction after several cycles. However, large specific capacity loss was observed after 20 cycles in all of the microstructures probably due to Mg-ion trapping in the host lattice. Furthermore, the effect of the cation (K <sup>+</sup>) present in the tunnel of Hollandite on Mg-ion diffusion was analyzed as well and it was concluded that tunnel cation could impede the movement of Mg-ion in host structure.</p>