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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Remusat, Laurent
French National Centre for Scientific Research
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2023Combination of ERDA, FTIR spectroscopy and NanoSIMS for the characterization of hydrogen incorporation in natural diamondscitations
- 2018Kinetic D/H fractionation during hydration and dehydration of silicate glasses, melts and nominally anhydrous mineralscitations
- 2018Long-term weathering rate of stained-glass windows using H and O isotopescitations
- 2016The composition of nanogranitoids in migmatites overlying the Ronda peridotites (Betic Cordillera, S Spain): the anatectic history of a polymetamorphic basementcitations
- 2014Isotopic and structural signature of experimentally irradiated organic mattercitations
- 2013Amorphization and D/H fractionation of kerogens during experimental electron irradiation: Comparison with chondritic organic mattercitations
- 2013Amorphization and D/H fractionation of kerogens during experimental electron irradiation: Comparison with chondritic organic mattercitations
- 2012High resolution TEM of chondritic carbonaceous matter: Metamorphic evolution and heterogeneitycitations
Places of action
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article
Combination of ERDA, FTIR spectroscopy and NanoSIMS for the characterization of hydrogen incorporation in natural diamonds
Abstract
Hydrogen is a volatile element involved in several geological processes ranging from rock weakening to the initiation of tectonic plates. Because it is present in diamond, the investigation of hydrogen content in natural diamonds could provide valuable information. Such studies are scarce despite hydrogen being among the main impurities in their structure. Using Elastic Recoil Detection Analysis, Fourier Transform Infrared spectroscopy and Nanoscale Secondary Ions Mass Spectrometry, we analyzed the incorporation of hydrogen in three diamonds growth habits: octahedral, cuboid and fibrous. Up to 25 wt. ppm of hydrogen was measured in some samples, placing hydrogen as the second most abundant impurity in natural diamonds after nitrogen and before boron. Comparison between the three methods indicates a difference in the main mode of hydrogen incorporation depending on the growth habit. Hydrogen is more readily incorporated in the fibrous and cuboid habits compared to the octahedral one. We also show that the incorporation of hydrogen is not correlated with the incorporation of nitrogen. Results suggest no chemical equilibration of hydrogen by diffusion through geological times and also confirm that not all hydrogen may be infrared active.