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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Peltola, Emilia
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2023Interface matters - Effects of catalyst layer metallurgy on macroscale morphology and electrochemical performance of carbon nanofiber electrodescitations
- 2022Nanoscale geometry determines mechanical biocompatibility of vertically aligned nanofiberscitations
- 2021Nanostructured Geometries Strongly Affect Fouling of Carbon Electrodescitations
- 2020Biofouling affects the redox kinetics of outer and inner sphere probes on carbon surfaces drastically differently - implications to biosensingcitations
- 2019Integrating Carbon Nanomaterials with Metals for Bio-sensing Applicationscitations
- 2019Fabrication of micro- and nanopillars from pyrolytic carbon and tetrahedral amorphous carboncitations
- 2018Unmodified and multi-walled carbon nanotube modified tetrahedral amorphous carbon (ta-C) films as in vivo sensor materials for sensitive and selective detection of dopaminecitations
- 2018Nanodiamonds on tetrahedral amorphous carbon significantly enhance dopamine detection and cell viabilitycitations
- 2017Amorphous carbon thin film electrodes with intrinsic Pt-gradient for hydrogen peroxide detectioncitations
- 2017Amorphous carbon thin film electrodes with intrinsic Pt-gradient for hydrogen peroxide detectioncitations
- 2017Carbon Nanostructure Based Platform for Enzymatic Glutamate Biosensorscitations
- 2017Nanodiamonds on tetrahedral amorphous carbon significantly enhance dopamine detection and cell viabilitycitations
- 2015Electrochemical detection of hydrogen peroxide on platinum-containing tetrahedral amorphous carbon sensors and evaluation of their biofouling propertiescitations
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article
Interface matters - Effects of catalyst layer metallurgy on macroscale morphology and electrochemical performance of carbon nanofiber electrodes
Abstract
Funding Information: This work was supported by funding from the Academy of Finland (#321996 and #328854) and Jane and Aatos Erkko Foundation. The authors acknowledge the provision of facilities and technical support by Aalto University at OtaNano - Nanomicroscopy Center (Aalto-NMC) and at Micronova Nanofabrication Centre. I.P. would like to thank Elli Leppänen and Petri Mustonen for discussions regarding the PECVD process, and Dr. Jani Sainio for help with sample characterization. Funding Information: This work was supported by funding from the Academy of Finland (# 321996 and # 328854 ) and Jane and Aatos Erkko Foundation . The authors acknowledge the provision of facilities and technical support by Aalto University at OtaNano - Nanomicroscopy Center (Aalto-NMC) and at Micronova Nanofabrication Centre. I.P. would like to thank Elli Leppänen and Petri Mustonen for discussions regarding the PECVD process, and Dr. Jani Sainio for help with sample characterization. Publisher Copyright: © 2022 The Author(s) ; The effect of catalyst materials and different process parameters on the growth of carbon nanofibers (CNFs) has been widely investigated. Typically, an adhesion metallization is required together with the catalyst to secure adequate attachment to the surface. The interactions within this multilayer structure and their effect on CNF growth and morphology has, however, not been thoroughly assessed. Thus, this work presents the growth behavior, the macroscale morphology, and the basic electrochemical characteristics of CNFs grown on two types of substrates - (1) Si + 80 nm Cr + 20 nm Ni, and (2) Si + 20 nm Ti + 20 nm Ni. Our results show that the macroscale geometric parameters of CNFs can be readily altered by using different adhesive layers. The inherently unstable Ti-Ni interface results in diffusion of Ni towards the silicon wafer to form silicide, which reduces the amount of available Ni for CNF nucleation, and therefore, the population density of fibers is reduced. On the other hand, the Cr-Ni interface ...