| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Pardanaud, Cedric
French National Centre for Scientific Research
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2022The role of defects, deuterium, and surface morphology on the optical response of berylliumcitations
- 2019Investigating the possible origin of Raman bands in defective sp2/sp3 carbons below 900 cm−1: Phonon density of states or double resonance mechanism at play?citations
- 2017Raman Microscopy : a Suitable Tool For Characterizing Surfaces in interaction With Plasmas in The Field of Nuclear Fusioncitations
- 2015In-plane and out-of-plane defects of graphite bombarded by H, D and He investigated by atomic force and Raman microscopiescitations
- 2014Multiwavelength Raman spectroscopy analysis of a large sampling of disordered carbons extracted from the Tore Supra tokamakcitations
- 2013Raman spectroscopy investigation of the H content of heated hard amorphous carbon layerscitations
- 2013Long Term H-Release from Amorphous Carbon Evidenced by in Situ Raman Microscopy under Isothermal Heatingcitations
- 2012Raman micro-spectroscopy as a tool to measure the absorption coefficient and the erosion rate of hydrogenated amorphous carbon films heat-treated under hydrogen bombardmentcitations
- 2011Raman study of CFC tiles extracted from the toroidal pump limiter of Tore Supracitations
Places of action
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article
Raman spectroscopy investigation of the H content of heated hard amorphous carbon layers
Abstract
We revisit here how Raman spectroscopy can be used to estimate the H content in hard hydrogenated amorphous carbon layers. The H content was varied from 2 at.% to 30 at.%, using heat treatments of a a-C:H, from room temperature to 1300 K and was determined independently using ion beam analysis. We examine the correlation of various Raman parameters and the consistency of their thermal evolution with thermo-desorption results. We identify a weak band at 860 cm-1 attributed to H bonded to C(sp2). We show that the HD/HG parameter (Height ratio between the D and G bands) is quasi-linear in the full range of H content and can thus be used to estimate the H content. Conversely, we show that the m/HG parameter (ratio between the photoluminescence background, m, and the height of the G band), often used to estimate the H content, should be used with care, first because it is sensitive to various photoluminescence quenching processes and second because it is not sensitive to H bonded to C(sp2).