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Rees, Neil
University of Birmingham
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2022Electrochemical metal recyclingcitations
- 2021Magnetically modified electrocatalysts for oxygen evolution reaction in proton exchange membrane (PEM) water electrolyzerscitations
- 2020Cisplatin adducts of DNA as precursors for nanostructured catalyst materialscitations
- 2016Enhancement of the hydrogen evolution reaction from Ni-MoS2 hybrid nanoclusterscitations
- 2015Investigating electrodes for intermediate temperature polymer electrolyte fuel cell (IT-PEFC)
- 2015Hydrogen selective membranescitations
- 2014Gas diffusion layer materials and their effect on polymer electrolyte fuel cell performance - Ex situ and in situ characterizationcitations
- 2013Gold microelectrode ensemblescitations
- 2011Electrode-nanoparticle collisionscitations
- 2011Nanoparticle-electrode collision processescitations
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article
Nanoparticle-electrode collision processes
Abstract
We report, for the first time, the bulk deposition (electroplating) of a metal onto nanoparticles during collisions with an inert electrode surface. Experiments show that for silver nanoparticles, multiple layers of Cd atoms can be electroplated onto the AgNPs from aqueous Cdduring collisions with a glassy carbon electrode held at a suitably reducing potential, and an average of 19 atomic layers of cadmium are found to be deposited in the few milliseconds that the NP is in contact with the electrode. For comparison, results are also presented for the underpotential deposition of Cd onto AgNPs under similar conditions.