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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Denissen, Paul Johan
Delft University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2022An integral non-intrusive electrochemical and in-situ optical technique for the study of the effectiveness of corrosion inhibitioncitations
- 2021When all intermetallics dealloy in AA2024-T3citations
- 2020In-situ Visual Quantification of Corrosion and Corrosion Protection
- 2020Corrosion Inhibition at Scribed Locations in Coated AA2024-T3 by Cerium- and DMTD-Loaded Natural Silica Microparticles under Continuous Immersion and Wet/Dry Cyclic Exposurecitations
- 2019Interpreting electrochemical noise and monitoring local corrosion by means of highly resolved spatiotemporal real-time opticscitations
- 2019Reducing subjectivity in EIS interpretation of corrosion and corrosion inhibition processes by in-situ optical analysiscitations
- 2017Cerium-loaded algae exoskeletons for active corrosion protection of coated AA2024-T3citations
Places of action
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article
When all intermetallics dealloy in AA2024-T3
Abstract
<p>A hyphenated optical-electrochemical technique and image analysis protocol is used to quantify global and local (intermetallic) corrosion process and kinetics. Our findings reveal an early stage (< 60 s) composition-dependent hierarchical local activation of all IMs that can be attributed to IM dealloying. This is followed by local trenching initiated at matrix locations adjacent to regions of the IMs previously dealloyed, which in turn develops into concentric trenching around the IMs. These stages have quantifiable activation times and kinetics. While dealloying kinetics are found to be strongly dependent on IM composition and slightly dependent on IM size in the case of the S-phases, trenching kinetics are IM composition and size independent.</p>