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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Abdelmoula, Mustapha
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2019Starch functionalized magnetite nanoparticles: New insight into the structural and magnetic propertiescitations
- 2019Starch functionalized magnetite nanoparticles: New insight into the structural and magnetic propertiescitations
- 2019Structure of single sheet iron oxides produced from surfactant interlayered green rustscitations
- 2018Abiotically or microbially mediated transformations of magnetite by sulphide species: The unforeseen role of nitrate-reducing bacteriacitations
- 2017Shale Of The Ivory Coast As A Filtration Material For Phosphate Removal From Waste Water
- 2017Biogenic Mineral Precipitation during Antimony bearing Ferrihydrite bioreduction
- 2012Application of magnetite catalyzed chemical oxidation (Fenton-like and persulfate) for the remediation of oil hydrocarbon contaminationcitations
- 2010In situ oxidation of green rusts by deprotonation; wet corrosion and passivation of weathering steelscitations
- 2009Arsenite sequestration at the surface of nano-Fe(OH)2, ferrous-carbonate hydroxide, and green-rust after bioreduction of arsenic-sorbed lepidocrocite by Shewanella putrefacienscitations
- 2009Arsenite sequestration at the surface of nano-Fe(OH)2, ferrous-carbonate hydroxide, and green-rust after bioreduction of arsenic-sorbed lepidocrocite by Shewanella putrefacienscitations
- 2008Aluminium substitution in iron(II–III)-layered double hydroxides: Formation and cationic ordercitations
- 2008Comparative studies of ferric green rust and ferrihydrite coated sand: Role of synthesis routescitations
Places of action
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article
Abiotically or microbially mediated transformations of magnetite by sulphide species: The unforeseen role of nitrate-reducing bacteria
Abstract
In the anoxic conditions of nuclear waste deep geological repository, the main iron corrosion products formed at the surface of the carbon steel overpacks are siderite (FeIICO3) and magnetite (FeIIFeIII2O4) that form a rather protective layer. The originality of this work is the consideration of the bacterial metabolism of nitrate-reducing bacteria (NRB), often overlooked in corrosion processes. Klebsiella mobilis was used as a model of NRB and incubated with ferrous carbonates/magnetite corrosion bilayers under anoxic conditions. As a consequence of a combination of biotic and abiotic processes magnetite was reduced to mackinawite (FeIIS) and subsequently transformed to greigite (FeIIFeIII2S4).