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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Wilson, Nick
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Topics
Publications (6/6 displayed)
- 2018An examination of the composition and microstructure of coarse intermetallic particles in AA2099-T8, including Li detectioncitations
- 2015The influence of rare earth mercaptoacetate on the initiation of corrosion on AA2024-T3 Part II: The influence of intermetallic compositions within heavily attacked sitescitations
- 2015The influence of rare earth mercaptoacetate on the initiation of corrosion on AA2024-T3 Part I: Average statistics of each intermetallic compositioncitations
- 2013A consistent description of intermetallic particle composition: An analysis of ten batches of AA2024-T3citations
- 2013Investigation into the influence of carbon contamination on the corrosion behavior of aluminum microelectrodes and AA2024-T3citations
- 2011Metal anode performance in low-temperature electrolytes for aluminum productioncitations
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article
The influence of rare earth mercaptoacetate on the initiation of corrosion on AA2024-T3 Part I: Average statistics of each intermetallic composition
Abstract
De-alloying of S-phase in AA2024-T3 in the presence chlorides, is well-known. However, it is unclear how rare earth mercaptoacetate inhibitors affect this process when immersed in a 0.1 M NaCl solution. This paper analyses data obtained using EPMA on AA2024-T3 surfaces before and after a 16 min immersion period. Cerium and praseodymium mercaptoacetate inhibited the de-alloying process of S-phase particles. Although no significant change in composition was observed for cathodic intermetallics, each appeared to participate in local corrosion reactions as evidenced by the development of surface oxides. Clustering between S-phase and one of the Cu-containing intermetallic domains was also evident.