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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Belhamel, Kamel
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Publications (5/5 displayed)
- 2013New zinc–rare earth alloys: Influence of intermetallic compounds on the corrosion resistancecitations
- 2013New zinc-rare earth alloys: Influence of intermetallic compounds on the corrosion resistancecitations
- 2011Corrosion behaviour of zinc-cerium alloys: role of intermetallic phasescitations
- 2010Selective extraction and determination of Au(III) by first-derivative Spectrophotometrycitations
- 2005Nickel Ion-Selective PVC Membrane Electrode Based on new tert-octyl Calix[6]arene Derivativecitations
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article
Corrosion behaviour of zinc-cerium alloys: role of intermetallic phases
Abstract
New zinc–cerium alloys (up to 5 wt.%) was synthesized and their corrosion behaviour was studied in a reference corrosive media. Metallographic analyses show that cerium is exclusively present in a Zn11Ce intermetallic phase, homogeneously dispersed in the zinc matrix. With an optimal concentration at around 1.5 wt.%, the Zn11Ce phase acts as a tank of cerium to form a protective Ce-enriched passive layer. Nevertheless, at high Ce content, the benefit in terms of corrosion resistance obtained by the incorporation of Ce in the corrosion layer is shaded by the galvanic coupling between the intermetallic phase and the matrix.