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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Salvage, Jonathan P.
University of Brighton
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2023Food-Inspired, High-Sensitivity Piezoresistive Graphene Hydrogelscitations
- 2023Smart Skins Based on Assembled Piezoresistive Networks of Sustainable Graphene Microcapsules for High Precision Health Diagnosticscitations
- 2022Nanosheet-Stabilized Emulsionscitations
- 2022Explosive percolation yields highly-conductive polymer nanocompositescitations
- 2021Role of release modifiers to modulate drug release from fused deposition modelling (FDM) 3D printed tabletscitations
- 2020Nanosheet-stabilized emulsions
- 2020Ultrasensitive Strain Gauges Enabled by Graphene-Stabilized Silicone Emulsionscitations
- 2018Carbon Nanofoam Supercapacitor Electrodes with Enhanced Performance Using a Water-Transfer Processcitations
- 2018Percolating metallic structures templated on laser-deposited carbon nanofoams derived from graphene oxide: applications in humidity sensingcitations
- 2012Microstructure changes of polyurethane by inclusion of chemically modified carbon nanotubes at low filler contentscitations
- 2012Synthesis and characterization of soybean-based hydrogels with an intrinsic activity on cell differentiation
Places of action
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article
Microstructure changes of polyurethane by inclusion of chemically modified carbon nanotubes at low filler contents
Abstract
The surface of multi-walled carbon nanotubes (MWCNTs) was modified to introduce acidic groups in either covalent or van der Waals interaction bonding environments to establish cross-linking sites with a host polymer. Nanocomposites based on a polyurethane matrix (PU) containing chemically functionalised multi-walled carbon nanotubes (MWCNTs) have been shown to alter its mechanical performance depending on the nature of the surface functional groups on MWCNTs, which correlates to the type of bonding interaction of the surface group and also the dispersibility of MWCNTs and their influence on the domain structure of polyurethane. The stress at break for nanocomposites containing 0.25wt% of acid-oxidised MWCNTs (MWCNT-ox), bearing covalently attached carboxylic, lactone and phenolic groups, was twice that of the native PU and Young's Modulus for the nanocomposites increased by four times. Whereas when hemin, which contains carboxylic functionality, was immobilised to the surface of pure MWCNTs, the improvement in Young's Modulus was only around twice that of pure PU. Differences in the disaggregation of MWCNTs into PU were observed between the samples as well as variation of the native domain structure of PU. The results also infer that the purification of MWCNTs from acid-oxidative lattice fragments (fulvic acids) is vital prior to conducting surface chemistry and polymerisation in order to ensure maximum mechanical performance enhancement in their reinforcement of the host polymer.