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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Lee, Koon-Yang
Imperial College London
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2023Predicting filling efficiency of composite resin injection repaircitations
- 2021<i>Komagataeibacter</i> Tool Kit (KTK): A Modular Cloning System for Multigene Constructs and Programmed Protein Secretion from Cellulose Producing Bacteria.citations
- 2020Nanomaterials Derived from Fungal Sources-Is It the New Hype?citations
- 2020Upcycling Poultry Feathers with (Nano)cellulose:Sustainable Composites Derived from Nonwoven Whole Feather Preformscitations
- 2020High porosity cellulose nanopapers as reinforcement in multi-layer epoxy laminatescitations
- 2019Nanocellulose reinforced polymer composites: Computational analysis of structure-mechanical properties relationshipscitations
- 2019Cationic starch as strengthening agent in nanofibrillated and bacterial cellulose nanopapers
- 2019Nanomaterials Derived from Fungal Sources - Is It the New Hype?citations
- 2018Better togethercitations
- 2018Thinner and better: (Ultra-)low grammage bacterial cellulose nanopaper-reinforced polylactide composite laminates
- 2017Sample geometry dependency on the measured tensile properties of cellulose nanopaperscitations
- 2016Understanding the Dispersion and Assembly of Bacterial Cellulose in Organic Solventscitations
- 2016Ductile unidirectional continuous rayon fibre-reinforced hierarchical compositescitations
- 2014Bacterial Cellulose Nanopaper as Reinforcement for Polylactide Compositescitations
- 2014Aligned unidirectional PLA/bacterial cellulose nanocomposite fibre reinforced PDLLA compositescitations
- 2014On the use of nanocellulose as reinforcement in polymer matrix compositescitations
- 2013Porous copolymers of ε-caprolactone as scaffolds for tissue engineeringcitations
- 2012Nano-fibrillated cellulose vs bacterial cellulose
- 2012Carbon Fiber: Properties, Testing, and Analysiscitations
- 2012Interfaces in Cross-Linked and Grafted Bacterial Cellulose/Poly(Lactic Acid) Resin Compositescitations
- 2012Nano-fibrillated cellulose vs bacterial cellulose:Reinforcing ability of nanocellulose obtained topdown or bottom-up
- 2009Renewable nanocomposite polymer foams synthesized from Pickering emulsion templatescitations
- 2009Surface functionalisation of bacterial cellulose as the route to produce green polylactide nanocomposites with improved propertiescitations
Places of action
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article
Surface functionalisation of bacterial cellulose as the route to produce green polylactide nanocomposites with improved properties
Abstract
The effect of surface functionalisation of bacterial cellulose nanofibrils (BC) and their use as reinforcement for polylactide (PLLA) nanocomposites was investigated. BC was functionalised with various organic acids via an esterification reaction. This rendered the otherwise hydrophilic BC hydrophobic and resulted in better compatibility (interfacial adhesion) between PLLA and BC. A direct wetting method, allowing the determination of the contact angle of polymer droplets on a single BC nanofibre, was developed to quantify the interfacial adhesion between PLLA and functionalised BC. It was found that the contact angle between PLLA droplets and functionalised BC decreased with increasing chain lengths of the organic acids used to hydrophobise BC. A novel method to compound BC with PLLA based on thermally induced phase separation (TIPS) to yield a dry form of pre-extrusion composite was also developed. The mechanical properties of the surface functionalised BC reinforced PLLA nanocomposites showed significant improvements when compared to neat PLLA and BC reinforced PLLA. The thermal degradation and viscoelastic behaviour of the nanocomposites were also improved over neat PLLA. (C) 2009 Elsevier Ltd. All rights reserved.