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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Baniasadi, Hossein
Aalto University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2024Polypyrrole-modified flax fiber sponge impregnated with fatty acids as bio-based form-stable phase change materials for enhanced thermal energy storage and conversioncitations
- 2024Polypyrrole-modified flax fiber sponge impregnated with fatty acids as bio-based form-stable phase change materials for enhanced thermal energy storage and conversioncitations
- 2024Fabrication of biocomposite materials with polycaprolactone and activated carbon extracted from agricultural wastecitations
- 2024Exploring the potential of regenerated Ioncell fiber composites: a sustainable alternative for high-strength applicationscitations
- 2024Elucidating the enduring transformations in cellulose-based carbon nanofibers through prolonged isothermal treatmentcitations
- 2024Wood flour and Kraft lignin enable air-drying of the nanocellulose-based 3D-printed structurescitations
- 2024Recycled carbon fiber reinforced composites: Enhancing mechanical properties through co-functionalization of carbon nanotube-bonded microfibrillated cellulosecitations
- 2024A cradle-to-gate life cycle assessment of polyamide-starch biocomposites: carbon footprint as an indicator of sustainabilitycitations
- 2023Strontium-Substituted Nanohydroxyapatite-Incorporated Poly(lactic acid) Composites for Orthopedic Applications: Bioactive, Machinable, and High-Strength Propertiescitations
- 2023Flexible and conductive nanofiber textiles for leakage-free electro-thermal energy conversion and storagecitations
- 2023Heat-Induced Actuator Fibers: Starch-Containing Biopolyamide Composites for Functional Textilescitations
- 2023High-concentration lignin biocomposites with low-melting point biopolyamidecitations
- 2023Innovative integration of pyrolyzed biomass into polyamide 11: Sustainable advancements through in situ polymerization for enhanced mechanical, thermal, and additive manufacturing propertiescitations
- 2021Exfoliated clay nanocomposites of renewable long-chain aliphatic polyamide through in-situ polymerizationcitations
- 2021Sustainable composites of surface-modified cellulose with low-melting point polyamidecitations
- 2021Novel long-chain aliphatic polyamide/surface-modified silicon dioxide nanocomposites: in-situ polymerization and propertiescitations
- 2021Alginate/cartilage extracellular matrix-based injectable interpenetrating polymer network hydrogel for cartilage tissue engineeringcitations
- 2021Selective Laser Sintering of Lignin-Based Compositescitations
- 20213D-Printed Thermoset Biocomposites Based on Forest Residues by Delayed Extrusion of Cold Masterbatch (DECMA)citations
- 2021High-Performance and Biobased Polyamide/Functionalized Graphene Oxide Nanocomposites through In Situ Polymerization for Engineering Applicationscitations
- 2015Investigation of thermomechanical properties of UHMWPE/graphene oxide nanocomposites prepared by in situ Ziegler–Natta polymerizationcitations
Places of action
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article
Exfoliated clay nanocomposites of renewable long-chain aliphatic polyamide through in-situ polymerization
Abstract
The current study was performed to synthesize a series of renewable polyamide 614/organoclay nanocomposites (PAC) with the improved structural, mechanical, and thermal properties via in-situ polymerization. The uniform dispersion and exfoliation of clay into the PA614 matrix, particularly at a lower loading of organoclay (less than 3%), confirmed via structural analyses (XRD, SEM, and TEM). Furthermore, the mechanical tests revealed remarkable improvement; namely, the tensile strength and storage modulus increased by 27% and 30%, respectively, in the sample contained 2% organoclay. Similarly, the TGA results showed a slight improvement in the thermal stability of the nanocomposite samples. Altogether, these improvements confirmed excellent compatibility between nanofiller and matrix and the organoclay homogenous dispersion into the PA matrix achieved by employing in-situ polymerization. Furthermore, all the samples illustrated a shear-thinning behavior over frequency attributed to the lack of time for the polymer chain to respond to the applied oscillation. Finally, the crystallinity of the samples diminished upon increasing the filler's content, which could be due to the decrease of free volume resulting from the presence of organoclay. To sum up, the current investigation supported the benefit of employing in-situ polymerization to synthesize renewable PA614/clay nanocomposites with enhanced physio-mechanical properties, which could be appropriate candidates for engineering applications.