693.932 PEOPLE
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Petrov, R. H. | Madrid |
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Clerck, Karen De
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Topics
Publications (36/36 displayed)
- 2025Comparison of distinctive polymeric membrane structures as support materials for membrane extraction of chiral aminescitations
- 2024Low-Velocity Impact Resistance and Compression After Impact Strength of Thermoplastic Nanofiber Toughened Carbon/Epoxy Composites with Different Layupscitations
- 2024Low-Velocity Impact Resistance and Compression After Impact Strength of Thermoplastic Nanofiber Toughened Carbon/Epoxy Composites with Different Layupscitations
- 2022Continuous fiber-reinforced aramid/PETG 3D-printed composites with high fiber loading through fused filament fabricationcitations
- 2021Building the third dimension : microstructure and mechanics of Additive Manufactured continuous Aramid fiber/PETG composites with variable fiber content through in-nozzle impregnation
- 2021Toughening mechanisms responsible for excellent crack resistance in thermoplastic nanofiber reinforced epoxies through in-situ optical and scanning electron microscopycitations
- 2021Fully integrated flexible dielectric monitoring sensor system for real-time in situ prediction of the degree of cure and glass transition temperature of an epoxy resincitations
- 2021Long-term stiffness prediction of particle filled polymers by dynamic mechanical analysis : frequency sweep versus creep methodcitations
- 2021Lifting the quality of fused filament fabrication of polylactic acid based compositescitations
- 2020Nanofibre toughening of dissimilar interfaces in compositescitations
- 2020The transferability and design of commercial printer settings in PLA/PBAT fused filament fabricationcitations
- 2020Influencing parameters on measurement accuracy in dynamic mechanical analysis of thermoplastic polymers and their compositescitations
- 2020Immiscibility of chemically alike amorphous polymers : phase separation of poly(2-ethyl-2-oxazoline) and poly(2‑n‑propyl-2- oxazoline)citations
- 2020Delamination resistant composites by interleaving bio-based long-chain polyamide nanofibers through optimal control of fiber diameter and fiber morphologycitations
- 2020Effect of interleaved polymer nanofibers on the properties of glass and carbon fiber compositescitations
- 2019Composite Materials: Excellent nanofiber adhesion for hybrid polymer materials with high toughness based on matrix interdiffusion during chemical conversion (Adv. Funct. Mater. 8/2019)citations
- 2019Interdiffusing core-shell nanofiber interleaved composites for excellent Mode I and Mode II delamination resistancecitations
- 2019Bio-material polylactic acid/poly(butylene adipate-co-terephthalate) blend developed for extrusion- based additive manufacturing
- 2019Improving mechanical properties for extrusion-based additive manufacturing of poly(lactic acid) by annealing and blending with poly(3-hydroxybutyrate)citations
- 2019Bio-material polylactic acid/poly(butylene adipate-co-terephthalate) blend development for extrusion-based additive manufacturing
- 2017Electrospun nanofibers for highly toughened fibre reinforced polymer composite laminates
- 2017Improved fatigue delamination behaviour of composite laminates with electrospun thermoplastic nanofibrous interleaves using the Central Cut-Ply methodcitations
- 2016Damage-resistant composites using electrospun nanofibers: a multiscale analysis of the toughening mechanismscitations
- 2016TOWARDS DAMAGE RESISTANT COMPOSITES USING ELECTROSPUN NANOFIBERS: A MULTISCALE ANALYSIS OF THE TOUGHENING MECHANISMS
- 2016Electrospinning of sacrificial nanofibers for the creation of a self-healing nanovascular network and its effect on the properties of an epoxy matrix
- 2016Interlaminar toughening of resin transfer molded laminates by electrospun polycaprolactone structures : effect of the interleave morphologycitations
- 2016Blend electrospinning of dye-functionalized chitosan and polycaprolactoe : towards biocompatible pH-sensors
- 2016Increasing the damage resistance of composites by interleaving them with electrospun nanofibrous veils
- 2015Using a polyester binder for the interlaminar toughening of glass/epoxy composite laminates
- 2013Electrospinning of nanofibers for functional textile applications
- 2013Modifying the crack growth in a glass fiber reinforced epoxy by adding polyamide 6 nanofibers
- 2012Blend electrospinning of chitosan/polycaprolactone nanofibres
- 2012The influence of polyamide 6 nanofibres on the mechanical properties of glass fibre/epoxy composites
- 2012The pH-sensitive properties of azo dyes in aqueous environment
- 2011Morphology study of polyamide 6.9 nanofibres electrospun under steady state conditions
- 2006Development of electroconductive polyacrylonitrile fibers through chemical metallization and galvanisationcitations
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article
Lifting the quality of fused filament fabrication of polylactic acid based composites
Abstract
The development of well-designed polylactic acid (PLA) based composite filaments through fused filament fabrication (FFF) is crucial, as PLA printed parts are characterized by a high brittleness. Here we focus on FFF composite formation using ductile poly (butylene adipate-co-terephthalate) (PBAT), the nanoclay cloisite and the chain extender Joncryl. A high modulus, flexibility, toughness and notched impact strength result upon combining PLA/PBAT (80:20; mass basis) with a sufficiently high cloisite amount (1-5 phr) supported by a suited Joncryl amount (0.3 phr). A fine PBAT dispersion is then ensured, as confirmed by scanning and transmission electron microscopy. For high cloisite amounts (e.g. 10 phr) the crystallinity and vicat softening temperature enhance but cloisite aggregation is unavoidable, leading to a strong reduction in tensile strain and toughness. Annealing increases crystallinity thus material strength, rigidity and impact, at least partially overruling the need of a fine dispersion. Novel radar charts are also reported to select an optimal bio-based blend suitable for different end-user applications by adjusting the composition and possible post-annealing of printed products.