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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Taheri, Peyman
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2023Extrusion-based 3D printing of biodegradable, osteogenic, paramagnetic, and porous FeMn-akermanite bone substitutescitations
- 2023Biodegradation of Oxide Nanoparticles in Apoferritin Protein Media: A Systematic Electrochemical Approachcitations
- 2022Extrusion-based additive manufacturing of Mg-Zn alloy scaffoldscitations
- 2022Additive manufacturing of bioactive and biodegradable porous iron-akermanite composites for bone regenerationcitations
- 2022Poly(2-ethyl-2-oxazoline) coating of additively manufactured biodegradable porous ironcitations
- 2021Nanoscopic and in-situ cross-sectional observations of Li-based conversion coating formation using liquid-phase TEMcitations
- 2021Extrusion-based 3D printing of ex situ-alloyed highly biodegradable MRI-friendly porous iron-manganese scaffoldscitations
- 2021Extrusion-based 3D printed biodegradable porous ironcitations
- 2021Simplistic correlations between molecular electronic properties and inhibition efficiencies: Do they really exist?citations
- 2020In-situ nanoscopic observations of dealloying-driven local corrosion from surface initiation to in-depth propagationcitations
- 2020Additively manufactured biodegradable porous zinccitations
- 2019Self-healing epoxy nanocomposite coatings based on dual-encapsulation of nano-carbon hollow spheres with film-forming resin and curing agentcitations
- 2019Mechanical and Corrosion Protection Properties of a Smart Composite Epoxy Coating with Dual-Encapsulated Epoxy/Polyamine in Carbon Nanospherescitations
- 2018Fabrication and characterization of graphene-based carbon hollow spheres for encapsulation of organic corrosion inhibitorscitations
- 2018Enhanced corrosion protection of mild steel by the synergetic effect of zinc aluminum polyphosphate and 2-mercaptobenzimidazole inhibitors incorporated in epoxy-polyamide coatingscitations
- 2017Improved corrosion resistance of aluminum brazing sheet by a post-brazing heat treatmentcitations
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article
Self-healing epoxy nanocomposite coatings based on dual-encapsulation of nano-carbon hollow spheres with film-forming resin and curing agent
Abstract
<p>The ability of an active protective organic coating to restore its protection functionality in case of a coating defect is of pivotal importance to ensure durable performance under demanding corrosive conditions. In this paper, a self-healing epoxy system is fabricated by separate encapsulation of epoxy and polyamine in carbon hollow spheres (CHSs) and the autonomous healing performance of the system applied on mild steel is investigated. CHSs were synthesized via a silica templating method using carbonization of polysaccharide shells formed on the surface of silica templates. Consequently, epoxy and polyamine were loaded in separate capsules by dispersion of CHSs into the dilute solutions of epoxy/acetone and polyamine/acetone respectively, under vacuum conditions. The synthesized CHSs were characterized before and after the silica removal using field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM). The CHSs loaded with the film forming agents were assessed using thermogravimetric analysis (TGA) and Fourier transform infrared (FTIR) spectroscopy. Furthermore, the protective and self-healing properties of the coatings fabricated were studied using electrochemical impedance spectroscopy (EIS), scanning vibrating electrode technique (SVET) and salt spray testing. The results showed that scribe defects in epoxy coatings with 10 wt % epoxy and polyamine capsules were healed effectively upon efficient release and subsequent recombination of the epoxy and polyamine agents reforming a protective layer at the damaged region.</p>