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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Zolotovskaya, Svetlana A.
University of Dundee
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2023Laser-engineered nanocomposites for SERS applications
- 2022Thiolated gamma-cyclodextrin-polymer-functionalized CeFe3O4 magnetic nanocomposite as an intrinsic nanocatalyst for the selective and ultrasensitive colorimetric detection of triacetone triperoxidecitations
- 2022Inkjet printing of high-concentration particle-free platinum inkscitations
- 2022Fabrication of a near-infrared fluorescence-emitting SiO2-AuZnFeSeS quantum dots-molecularly imprinted polymer nanocomposite for the ultrasensitive fluorescence detection of levamisolecitations
- 2022Fabrication of a near-infrared fluorescence-emitting SiO2-AuZnFeSeS quantum dots-molecularly imprinted polymer nanocomposite for the ultrasensitive fluorescence detection of levamisolecitations
- 2021Controlled metallization of ion-exchanged glasses by thermal polingcitations
- 2020Aptamer-based cocaine assay using a nanohybrid composed of ZnS/Ag2Se quantum dots, graphene oxide and gold nanoparticles as a fluorescent probecitations
- 2020Nanosecond Laser Surface Silver Metallization of Wet Ion Exchanged Glassescitations
- 2016On second harmonic generation and multiphoton-absorption induced luminescence from laser-reshaped silver nanoparticles embedded in glasscitations
- 2016Sensing platform based on laser-engineered nanocomposite glass
- 2015Plasmonics for rapid laser micro-joining of dielectrics
- 2015Novel metal-glass-nanocomposite based substrates for Surface-Enhanced Raman Spectroscopy
- 2015Radially and azimuthally polarized laser induced shape transformation of embedded metallic nanoparticles in glasscitations
- 2014Controlled modification of optical and structural properties of glass with embedded silver nanoparticles by nanosecond pulsed laser irradiationcitations
- 2014A Novel ‘Metamaterial’ for Electro-Optic Electron Bunch Profile Monitors
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article
Fabrication of a near-infrared fluorescence-emitting SiO2-AuZnFeSeS quantum dots-molecularly imprinted polymer nanocomposite for the ultrasensitive fluorescence detection of levamisole
Abstract
Levamisole is an anthelminthic drug that is usually used as a cutting agent to lace illicit cocaine samples and has been classified as a dangerous substance. In this work, we report on the fabrication of a novel fluorescence sensor for levamisole using AuZnFeSeS alloyed quantum dots (QDs)-molecularly imprinted polymer (MIP) nanocomposite. Firstly, organic-phased AuZnFeSeS QDswere synthesized via the organometallic hot-injection pyrolysis of metal precursors, surfactants, and organic ligands. Silica (SiO2) was then encapsulated on the QDs surface to render it compact, stable, and biocompatible. Via a free radical polymerization approach, a robust MIP shell templated with levamisole was coated around the SiO2-AuZnFeSeS QDs surface to form a AuZnFeSeS QDs@MIP core/shell nanocomposite. Passivation of the SiO2-AuZnFeSeS QDs core surface with the MIP shell led to radiative exciton recombination process, whereby the QDs fluorescence was enhanced. Interestingly, the SiO2-AuZnFeSeS QDs was characterized by rod-shaped and spherical-shaped particle morphology. Under optimum conditions, the fluorescence of the AuZnFeSeS QDs@MIP nanocomposite was quenched in the presence of levamisole and was selective against other tested drugs. Quantitative detection was achieved in the concentration range of 0.5 – 100 μM with a limit of detection of 0.05 μM (47.4 nM). Validation of the MIP-levamisole affinity was demonstrated by the superior sensitivity of the AuZnFeSeS QDs@MIP over the AuZnFeSeS QDs@NIP (non-templated material). Levamisole was successfully detected in a mixed drug sample containing cocaine with satisfactory analytical recoveries. This work is the first reported use of a cadmium-free quintenary alloyed QDs@MIP nanocomposite fluorescence detection system for levamisole.