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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Velikov, Krassimir Petkov
University of Amsterdam
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2024Thermoresponsive oil-continuous gels based on double-interpenetrating colloidal-particle networkscitations
- 2023Towards a constitutive relation for emulsions exhibiting a yield stresscitations
- 2023Influence of thickeners (microfibrillated cellulose, starch, xanthan gum) on rheological, tribological and sensory properties of low-fat mayonnaisescitations
- 2022Ethyl cellulose nanoparticles as stabilizers for Pickering emulsionscitations
- 2022Elastic reinforcement and yielding of starch-filled lipid gelscitations
- 2022Unravelling discolouration caused by iron-flavonoid interactionscitations
- 2020Multivalent ion-induced re-entrant transition of carboxylated cellulose nanofibrils and its influence on nanomaterials' propertiescitations
- 2019Biobased Cellulose Nanofibril–Oil Composite Films for Active Edible Barrierscitations
- 2019Cellulose microfibril networks in hydrolysed soy protein isolate solutionscitations
- 2017Revealing and Quantifying the Three-Dimensional Nano- and Microscale Structures in Self-Assembled Cellulose Microfibrils in Dispersionscitations
- 2015Microstructure and rheology of microfibril-polymer networkscitations
- 2014Phase transitions in cellulose microfibril dispersions by high-energy mechanical deagglomerationcitations
- 2003Synthesis and characterization of large colloidal silver particlescitations
Places of action
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article
Ethyl cellulose nanoparticles as stabilizers for Pickering emulsions
Abstract
Pickering emulsions stabilized by ethyl cellulose nanoparticles have recently received –great attention for their remarkable stability and numerous industrial applications. De- spite this, the exact stabilization mechanism of such Pickering emulsions is still not fully understood. Both the stabilization of the emulsion by particle adsorption at the inter- face and through network formation in the continuous phase (leading to a yield stress) have been suggested. In this work we study soybean oil-in-water emulsions stabilized by ethyl cellulose nanoparticles and find, by the use of confocal microscopy and interfa- cial tension measurements, that the main stabilization mechanism of this nanoparticle- stabilized emulsions is the adsorption of the particles at the interface, instead of forming a network in the continuous phase. At the same time, oscillatory rheology measurements reveal that the emulsions exhibit a yield stress well below the random close-packing limit for hard spheres, suggesting short-range interactions between the droplets caused by the presence of the particles at the interface. The presence of the particles at the interface in combination with the observed rheological behavior of an attractive emulsion gives a strong indication for a particle-bridged stabilized emulsions.