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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Adegoke, Oluwasesan
University of Dundee
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (35/35 displayed)
- 2024Insight into the electrochemical performance of heavy metal-free quantum dots in different buffered ferricyanide/ferrocyanide redox systemscitations
- 2024Molecularly Imprinted Viral Protein Integrated Zn−Cu−In−Se−P Quantum Dots Superlattice for Quantitative Ratiometric Electrochemical Detection of SARS-CoV‑2 Spike Protein in Salivacitations
- 2024An organic-inorganic polyacrylamide-based surface imprinted quantum dots for the impedimetric and voltammetric detection of diazepam in saliva with smartphone readoutcitations
- 2024Molecularly Imprinted Viral Protein Integrated Zn-Cu-In-Se-P Quantum Dots Superlattice for Quantitative Ratiometric Electrochemical Detection of SARS-COV-2 Spike Protein in Salivacitations
- 2024Molecularly imprinted viral protein integrated Zn-Cu-In-Se-P quantum dots superlattice for quantitative ratiometric electrochemical detection of SARS-CoV-2 spike protein in salivacitations
- 2024Heavy metal-free MnInPSeS alloyed quantum dots-molecularly imprinted polymer as an electrochemical nanosensor for the detection of the synthetic cathinone, 3,4-methylenedioxypyrovaleronecitations
- 2024Heavy metal-free MnInPSeS alloyed quantum dots-molecularly imprinted polymer as an electrochemical nanosensor for the detection of the synthetic cathinone, 3,4-methylenedioxypyrovaleronecitations
- 2023Cadmium-free silica-encapsulated molecularly imprinted AuZnCeSeS quantum dots nanocomposite as an ultrasensitive fluorescence nanosensor for methamphetamine detectioncitations
- 2023Blue-emitting SiO 2 -coated Si-doped ZnSeS quantum dots conjugated aptamer-molecular beacon as an electrochemical and metal-enhanced fluorescence biosensor for SARS-CoV-2 spike proteincitations
- 2023Blue-emitting SiO2-coated Si-doped ZnSeS quantum dots conjugated aptamer-molecular beacon as an electrochemical and metal-enhanced fluorescence biosensor for SARS-CoV-2 spike proteincitations
- 2022Thiolated gamma-cyclodextrin-polymer-functionalized CeFe3O4 magnetic nanocomposite as an intrinsic nanocatalyst for the selective and ultrasensitive colorimetric detection of triacetone triperoxidecitations
- 2022Alloyed AuFeZnSe quantum dots@gold nanorod nanocomposite as an ultrasensitive and selective plasmon-amplified fluorescence OFF-ON aptasensor for arsenic (III)citations
- 2022Alloyed AuFeZnSe quantum dots@gold nanorod nanocomposite as an ultrasensitive and selective plasmon-amplified fluorescence OFF-ON aptasensor for arsenic (III)citations
- 2022Thiolated gamma-cyclodextrin-polymer-functionalized CeFe 3 O 4 magnetic nanocomposite as an intrinsic nanocatalyst for the selective and ultrasensitive colorimetric detection of triacetone triperoxidecitations
- 2022Fabrication of a near-infrared fluorescence-emitting SiO2-AuZnFeSeS quantum dots-molecularly imprinted polymer nanocomposite for the ultrasensitive fluorescence detection of levamisolecitations
- 2022Fabrication of a near-infrared fluorescence-emitting SiO2-AuZnFeSeS quantum dots-molecularly imprinted polymer nanocomposite for the ultrasensitive fluorescence detection of levamisolecitations
- 2021Organometallic synthesis, structural and optical properties of CdSe quantum dots passivated with ternary AgZnS alloyed shellcitations
- 2021Polymeric-coated Fe-doped ceria/gold hybrid nanocomposite as an aptasensor for the catalytic enhanced colorimetric detection of 2,4-dinitrophenolcitations
- 2021Polymeric-coated Fe-doped ceria/gold hybrid nanocomposite as an aptasensor for the catalytic enhanced colorimetric detection of 2,4-dinitrophenolcitations
- 2020Aptamer-based cocaine assay using a nanohybrid composed of ZnS/Ag2Se quantum dots, graphene oxide and gold nanoparticles as a fluorescent probecitations
- 2020Fluorometric virus detection platform using quantum dots-gold nanocomposites optimizing the linker length variationcitations
- 2020Fluorometric virus detection platform using quantum dots-gold nanocomposites optimizing the linker length variationcitations
- 2019Passivating effect of ternary alloyed AgZnSe shell layer on the structural and luminescent properties of CdS quantum dotscitations
- 2019Multi-shaped cationic gold nanoparticle-L-cysteine-ZnSeS quantum dots hybrid nanozyme as an intrinsic peroxidase mimic for the rapid colorimetric detection of cocainecitations
- 2019Multi-shaped cationic gold nanoparticle-L-cysteine-ZnSeS quantum dots hybrid nanozyme as an intrinsic peroxidase mimic for the rapid colorimetric detection of cocainecitations
- 2018Single-step detection of norovirus tuning localized surface plasmon resonance-induced optical signal between gold nanoparticles and quantum dotscitations
- 2017Bright luminescent optically engineered core/alloyed shell quantum dotscitations
- 2017Alloyed quaternary/binary core/shell quantum dot-graphene oxide nanocomposite:Preparation, characterization and application as a fluorescence “switch ON” probe for environmental pollutantscitations
- 2017Alloyed quaternary/binary core/shell quantum dot-graphene oxide nanocompositecitations
- 2017Bright luminescent optically engineered core/alloyed shell quantum dots: an ultrasensitive signal transducer for dengue virus RNA via localized surface plasmon resonance-induced hairpin hybridizationcitations
- 2016Gradient band gap engineered alloyed quaternary/ternary CdZnSeS/ZnSeS quantum dotscitations
- 2016L-cysteine-capped core/shell/shell quantum dot-graphene oxide nanocomposite fluorescence probe for polycyclic aromatic hydrocarbon detectioncitations
- 2016Size-confined fixed-composition and composition-dependent engineered band gap alloying induces different internal structures in L-cysteine-capped alloyed quaternary CdZnTeS quantum dotscitations
- 2016Fluorescence properties of alloyed ZnSeS quantum dots overcoated with ZnTe and ZnTe/ZnS shellscitations
- 2015Optical properties of water-soluble l-cysteine-capped alloyed CdSeS quantum dot passivated with ZnSeTe and ZnSeTe/ZnS shellscitations
Places of action
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article
Polymeric-coated Fe-doped ceria/gold hybrid nanocomposite as an aptasensor for the catalytic enhanced colorimetric detection of 2,4-dinitrophenol
Abstract
The Meisenheimer charge transfer reaction has, for many years, been the predominant mode of interaction to detect explosive compounds via the naked eye. However, this method is majorly sensitive to 2,4,6-trinitrotoluene and insensitive to many other explosive compounds. In this work, we report on the development of a novel aptamer-based amphiphilic polymer-coated Fe-doped ceria/gold (Au) hybrid nanocomposite (NC) as a peroxidase mimetic nanozyme for explosive colorimetric detection. Polymeric-Fe-doped ceria NC was synthesized and incorporated in-situ in the hydrothermal synthetic pot of citrate-Au nanoparticles to form a polymer-Fe-doped ceria/Au NC. A streptavidin (strep)-biotinylated DNA aptamer (B-Apt) binding complex was immobilised on<br/>the polymer-Fe-doped ceria/Au NC surface and the modified NC was used as a functional nanozyme in a peroxidase mimic assay to catalyse the oxidation of 3,3′,5,5′-tetramethylbenzidine by H2O2. Screening of several explosives showed that 2,4-dinitrophenol (DNP) bonded with higher affinity to the aptamer based on the selective greenish colorimetric catalytic reaction observed. The peroxidase mimetic activities of several nanozymes were tested and our analysis showed that the polymer-Fe-doped ceria/Au NC generated enhanced catalytic activity for DNP detection. Several optimisation reactions including the kinetic reaction mechanism was conducted and a limit of detection of 0.45 µg/mL (2.4 µM) was obtained for DNP recognition. The peroxidase mimetic strep-B-Apt-polymer-Fe-doped ceria/Au NC biosensor was successfully applied for the detection of DNP in tap water and river water with satisfactory recoveries in the range of 97–117%.