| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Muir, Ben
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2020Lipid Nanodiscs via Ordered Copolymerscitations
- 2020Analyzing 3D Hyperspectral ToF-SIMS Depth Profile Data Using Self-Organizing Map-Relational Perspective Mappingcitations
- 2018Distinguishing chemically similar polyamide materials with ToF-SIMS using self-organizing maps and a universal data matrixcitations
- 2017Limitations with solvent exchange methods for synthesis of colloidalfullerenescitations
- 2016Probing the interfacial structure of bilayer plasma polymer films via neutron reflectometry
- 2016Investigation of the growth mechanisms of diglyme plasma polymers on amyloid fibril networkscitations
- 2016Chromium functionalized diglyme plasma polymer coating enhances enzyme-linked immunosorbent assay performancecitations
- 2015Protic ionic liquids (PILs) nanostructure and physicochemical properties: development of high-throughput methodology for PIL creation and property screenscitations
- 2014Water-dispersible magnetic carbon nanotubes as T2-weighted MRI contrast agentscitations
- 2014A study of the initial film growth of PEG-like plasma polymer films via XPS and NEXAFScitations
Places of action
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article
Limitations with solvent exchange methods for synthesis of colloidalfullerenes
Abstract
We have demonstrated that the use of tetrahydrofuran (THF) as a solvent to produce dispersed, water soluble fullerenes results in significant oxidation and degradation of the fullerene cage, which has not been reported previously. We also report a new finding that the use of N, N-dimethylformamide (DMF) can also generate stabilised fullerene (C60) nanoparticle dispersions in aqueous solutions including water and phosphate buffered saline (PBS) buffer. We compare this new DMF method with the well-known THF method following an extensive chemical and physical analysis of the resulting nanoparticles. The exact mechanism of action behind this oxidation and degradation is unknown, however, the role of peroxides is likely. The method of solvent exchange based on the use of DMF results in the formation of fullerene nanoparticle agglomerates that are highly stable in PBS and water, while the THF agglomerates are only stable in water. However, caution should be applied when using these approaches due to the significant degradation of the fullerene cage observed when using various techniques such as dynamic light scattering (DLS), matrix assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF), X-ray photoelectron spectroscopy (XPS), X-ray powder diffraction (XRD), fourier transform infrared spectroscopy (FTIR), proton nuclear magnetic resonance (1H NMR) and cryo transmission electron microscopy (cryo-TEM). Our results show that the solvent exchange technique using THF results in partial oxida-tion and degradation of C60, interestingly, the DMF evaporative method results in greater oxidation and degradation of C60 but significantly enhanced colloidal stability in buffer.