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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Simon, Frank
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2023Antimicrobial Brushes on Titanium via “Grafting to” Using Phosphonic Acid/Pyridinium Containing Block Copolymerscitations
- 2023Mineral-impregnated carbon-fiber based reinforcing grids as thermal energy harvesters: A proof-of-concept study towards multifunctional building materialscitations
- 2023Screen printable PANI/carbide-derived carbon supercapacitor electrode ink with chitosan bindercitations
- 2021The Localization Behavior of Different CNTs in PC/SAN Blends Containing a Reactive Componentcitations
- 2020Bio-inspired deposition of electrochemically exfoliated graphene layers for electrical resistance heating applicationscitations
- 2019Elucidating the Chemistry behind the Reduction of Graphene Oxide Using a Green Approach with Polydopaminecitations
- 2018Electrolytic surface treatment for improved adhesion between carbon fibre and polycarbonatecitations
- 2018Electrolytic surface treatment for improved adhesion between carbon fibre and polycarbonate
- 2016Structure-property relations in semifluorinated poly(methacrylate)scitations
- 2016Gold aerogels: Three-dimensional assembly of nanoparticles and their use as electrocatalytic interfacescitations
- 2015Polyelectrolytes to promote adhesive bonds of laser-structured aluminiumcitations
- 2013Poly(lactic acid) composites with poly(lactic acid)-modified carbon nanotubescitations
- 2010Studying the influence of chemical structure on the surface properties of polymer filmscitations
- 2010Poly(2-(dimethylamino)ethyl methacrylate) brushes with incorporated nanoparticles as a SERS active sensing layercitations
- 2007Multiwalled Carbon Nanotubes Produced by a Continuous CVD Method and Their Use in Melt Mixed Composites with Polycarbonate
Places of action
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article
Studying the influence of chemical structure on the surface properties of polymer films
Abstract
<p>The influence of the chemical structure of polymer surfaces with systematically altered chemical composition (aliphatic, aromatic, ester group in the side chain/main chain, ether- and sulfone groups), among them new polymeric structure synthesized in our group, on the surface properties was examined using carefully synthesized and purified polymers. The aim of the research was to elaborate direct structure-property relationships between the chemical structure and parameters describing the surface properties, such as wetting, surface free energy and adsorption of proteins. Thin films were prepared by spin coating and characterized with a combination of complementary methods (optical microscopy, AFM, contact angle measurements, streaming potential measurements, XPS, ellipsometry). Finding correlations required pure and well-characterized polymers as well as the formation of smooth, thin films with low surface roughness. The chemical structure of the polymers used gave rise to a broad range of surface free energies varying from 9.8 to 40.0. mN/m. The adsorption of human serum albumin as model protein on these films was determined by using a static method, the high performance liquid chromatography technique (HPLC). In tendency a correlation between chemical structure (represented by the ratio between oxygen and carbon), surface free energy and amount of adsorbed HSA could be derived.</p>