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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Vasić, Milica
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Publications (8/8 displayed)
- 2024New Eco-Cements Made with Marabou Weed Biomass Ashcitations
- 2023Negative impacts of petroleum coke as an energy source in the brick-making industrycitations
- 2023Application of pyrophyllite in high-temperature treated building materialscitations
- 2022Alkali-activated geopolymerization of a low illitic raw clay and waste brick mixture. An alternative to traditional ceramicscitations
- 2022Structure and properties of ZnO/ZnMn2O4 composite obtained by thermal decomposition of terephthalate precursor
- 2022Application of pyrophyllite in building and refractory ceramic materials
- 2021The Influence of Thermal Treatment on the Formation Mechanism of the Cu, Fe-Containing Nanocomposite Material Synthesized by the Sol–Gel Methodcitations
- 2020XRD and FTIR investigation of the structural and phase transformations of the composite material containing α-Fe2O3/CuFe2O4 phases in silica matrix
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article
Alkali-activated geopolymerization of a low illitic raw clay and waste brick mixture. An alternative to traditional ceramics
Abstract
Geopolymerization was investigated as an alternative to traditional ceramic products by developing a more sustainable approach that avoids thermal treatment. The study presents the first known alkali-activation of a raw clay and waste clay brick mixture using the solid to liquid ratios of 2.33 and 2.78. Several experimental sets were prepared to harden under varying conditions (2–4 days drying in 60 °C–70 °C and 3 h steam-curing). Non-activated and activated samples were analyzed for their physical and chemical properties after 14, 21, and 28 days. The tile-shaped specimens exhibited better initial drying behavior than the cubes and produced stronger materials with fewer cracks. Pre-curing in steam conditions induced higher flexural strength (13.7 MPa) and water absorption (13.13%) for the geopolymer tiles. The highest Si/Al molar ratio in the amorphous portion of 5.78 induced the best flexural strength. The geopolymerization process showed microstructural changes associated with the appearance of fibrous Na-zeolite nanocrystals. Ongoing reactions of amorphization in the bulk material and further crystallization at the surface are documented after 6 months of curing. This first detailed study reveals that the production of geopolymer ceramics from brick waste is possible, but further optimization of the activating solution and curing parameters is required.