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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Madeira, Lm
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2023Fe-containing carbon-coated monoliths prepared by CVD in gaseous toluene abatement-parametric analysis of the Fenton processcitations
- 2022Gaseous toluene abatement by the heterogeneous Fenton-like process using iron/carbon-coated monolith as catalyst: Proof of conceptcitations
- 2022Unravelling the relation between processed crude oils and the composition of spent caustic effluents as well as the respective economic impactcitations
- 2019Low temperature glycerol steam reforming over a Rh-based catalyst combined with oxidative regenerationcitations
- 2016Chemical and photochemical degradation of polybrominated diphenyl ethers in liquid systems - A reviewcitations
- 2014Azo-dye orange II degradation by the heterogeneous Fenton-like process using a zeolite Y-Fe catalyst-Kinetics with a model based on the Fermi's equationcitations
- 2014Removal of paraquat pesticide with Fenton reaction in a pilot scale water systemcitations
- 2014Boehmite-phenolic resin carbon molecular sieve membranes-Permeation and adsorption studiescitations
- 2013Influence of the iron precursor in the preparation of heterogeneous Fe/activated carbon Fenton-like catalystscitations
- 2013Drinking water and biofilm disinfection by Fenton-like reactioncitations
- 2010Enhancing the production of hydrogen via water-gas shift reaction using Pd-based membrane reactorscitations
- 2007Azo-dye Orange II degradation by heterogeneous Fenton-like reaction using carbon-Fe catalystscitations
- 2005Proton electrolyte membrane properties and direct methanol fuel cell performance II. Fuel cell performance and membrane properties effectscitations
- 2005Performance and efficiency of a DMFC using non-fluorinated composite membranes operating at low/medium temperaturescitations
- 2002New evidences of redox mechanism in n-butane oxidative dehydrogenation over undoped and Cs-doped nickel molybdatescitations
Places of action
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article
Boehmite-phenolic resin carbon molecular sieve membranes-Permeation and adsorption studies
Abstract
Composite carbon molecular sieve membranes (c-CMSM) were prepared in a single dipping-drying-carbonization step from phenolic resin solutions (12.5-15 wt.%) loaded with boehmite nanoparticles (0.5-1.2 wt.%). A carbon matrix with well-dispersed Al2O3 nanowires was formed from the decomposition of the resin and dehydroxylation of boehmite. The effect of the carbon/Al(2)O(3)ratio on the porous structure of the c-CMSM was accessed based on the pore size distribution and gas permeation toward N-2, O-2, CO2, He, H-2, C3H6 and C3H8. c-CMSM with higher carbon/Al2O3 ratios had a more open porous structure, exhibiting higher permeabilities and lower permselectivities. c-CMSM performance was above the upper bound curves for polymeric membranes for several gas pairs, particularly for C3H6/C3H8 (permeability toward C3H6 of 420 barrer and permselectivity of 18.1 for a c-CMSM with carbon/Al2O3 ratio of 4.4). Unsupported films were also prepared (carbon/Al(2)O(3)ratio 7.3) and crushed into small flakes. Equilibrium isotherms of H-2, N-2, O-2, CO2, C3H8 and C3H6 at 293 K were determined on these flakes to obtain the kinetic and adsorption selectivities toward gas pairs of interest; obtained adsorption and diffusion coefficients accurately predicted the permeabilities of all studied gases except CO2 (experimental and predicted permeabilities of 1148 and 154 barrer, respectively).