| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Schroder, Martin
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2024Electron Beam and Thermal Stabilities of MFM-300(M) Metal-Organic Frameworkscitations
- 2022Adsorption of sulphur dioxide in Cu(II)-carboxylate framework materials: the role of ligand functionalisation and open metal sites
- 2022Direct visualisation of supramolecular binding and separation of light hydrocarbons in MFM-300(In)
- 2022How Reproducible are Surface Areas Calculated from the BET Equation?citations
- 2021High Ammonia Adsorption in MFM-300 Materials:Dynamics and Charge Transfer in Host–Guest Bindingcitations
- 2021High Ammonia Adsorption in MFM-300 Materialscitations
- 2021How Reproducible Are Surface Areas Calculated from the BET Equation?citations
- 2021Catalytic decomposition of NO2 over a copper-decorated metal–organic framework by non-thermal plasmacitations
- 2021Atomically-dispersed copper sites in a metal-organic framework for reduction of nitrogen dioxide
- 2021Simultaneous Neutron Powder Diffraction and Microwave Characterisation at Elevated Temperatures
- 2020Quantitative Electro-Reduction of CO2 to Liquid Fuel over Electro-Synthesized Metal-Organic Frameworkscitations
- 2020Quantitative Electro-Reduction of CO2 to Liquid Fuel over Electro-Synthesized Metal-Organic Frameworkscitations
- 2019Iodine adsorption in a redox-active metal-organic frameworkcitations
- 2019Iodine adsorption in a redox-active metal-organic framework:Electrical conductivity induced by host-guest charge-transfercitations
- 2018Ammonia Storage by Reversible Host-Guest Site Exchange in a Robust Metal-Organic Frameworkcitations
- 2018Ammonia Storage by Reversible Host-Guest Site Exchange in a Robust Metal-Organic Frameworkcitations
- 2018High Volumetric Hydrogen Adsorption in a Porous Anthracene-decorated Metal–Organic Frameworkcitations
- 2018High Volumetric Hydrogen Adsorption in a Porous Anthracene-decorated Metal–Organic Frameworkcitations
- 2017Stepwise Observation and Quantification and Mixed Matrix Membrane Separation of CO2 within a Hydroxy-Decorated Porous Hostcitations
- 2017Porous Metal–Organic Polyhedral Frameworks with Optimal Molecular Dynamics and Pore Geometry for Methane Storagecitations
- 2014Inelastic neutron scattering study of binding of para-hydrogen in an ultra-microporous metal–organic frameworkcitations
- 2013Five coordinate M(II)-diphenolate [M = Zn(II), Ni(II), and Cu(II)] Schiff base complexes exhibiting metal-and ligand-based redox chemistrycitations
- 2008Metal-directed columnar phase formation in tetrahedral zinc(II) and manganese(II) metallomesogenscitations
Places of action
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article
Inelastic neutron scattering study of binding of para-hydrogen in an ultra-microporous metal–organic framework
Abstract
Metal–organic framework (MOF) materials show promise for H2 storage and it is widely predicted by computational modelling that MOFs incorporating ultra-micropores are optimal for H2 binding due to enhanced overlapping potentials. We report the investigation using inelastic neutron scattering of the interaction of H2 in an ultra-microporous MOF material showing low H2 uptake capacity. The study has revealed that adsorbed H2 at 5 K has a liquid recoil motion along the channel with very little interaction with the MOF host, consistent with the observed low uptake. The low H2 uptake is not due to incomplete activation or decomposition as the desolvated MOF shows CO2 uptake with a measured pore volume close to that of the single crystal pore volume. This study represents a unique example of surprisingly low H2 uptake within a MOF material, and complements the wide range of studies on systems showing higher uptake capacities and binding interactions.