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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Zolotovskaya, Svetlana A.
University of Dundee
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2023Laser-engineered nanocomposites for SERS applications
- 2022Thiolated gamma-cyclodextrin-polymer-functionalized CeFe3O4 magnetic nanocomposite as an intrinsic nanocatalyst for the selective and ultrasensitive colorimetric detection of triacetone triperoxidecitations
- 2022Inkjet printing of high-concentration particle-free platinum inkscitations
- 2022Fabrication of a near-infrared fluorescence-emitting SiO2-AuZnFeSeS quantum dots-molecularly imprinted polymer nanocomposite for the ultrasensitive fluorescence detection of levamisolecitations
- 2022Fabrication of a near-infrared fluorescence-emitting SiO2-AuZnFeSeS quantum dots-molecularly imprinted polymer nanocomposite for the ultrasensitive fluorescence detection of levamisolecitations
- 2021Controlled metallization of ion-exchanged glasses by thermal polingcitations
- 2020Aptamer-based cocaine assay using a nanohybrid composed of ZnS/Ag2Se quantum dots, graphene oxide and gold nanoparticles as a fluorescent probecitations
- 2020Nanosecond Laser Surface Silver Metallization of Wet Ion Exchanged Glassescitations
- 2016On second harmonic generation and multiphoton-absorption induced luminescence from laser-reshaped silver nanoparticles embedded in glasscitations
- 2016Sensing platform based on laser-engineered nanocomposite glass
- 2015Plasmonics for rapid laser micro-joining of dielectrics
- 2015Novel metal-glass-nanocomposite based substrates for Surface-Enhanced Raman Spectroscopy
- 2015Radially and azimuthally polarized laser induced shape transformation of embedded metallic nanoparticles in glasscitations
- 2014Controlled modification of optical and structural properties of glass with embedded silver nanoparticles by nanosecond pulsed laser irradiationcitations
- 2014A Novel ‘Metamaterial’ for Electro-Optic Electron Bunch Profile Monitors
Places of action
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article
Thiolated gamma-cyclodextrin-polymer-functionalized CeFe3O4 magnetic nanocomposite as an intrinsic nanocatalyst for the selective and ultrasensitive colorimetric detection of triacetone triperoxide
Abstract
Explosives are powerful destructive weapons used by criminals and terrorists across the globe and their use within military installation sites poses serious environmental health problems. Existing colorimetric sensors for triacetone triperoxide (TATP) relies on detecting its hydrolysed H2O2 form. However, such detection strategy limits the practicability for on-site TATP sensing. In this work, we have developed a novel peroxidase mimic catalytic colorimetric sensor for direct recognition of TATP. Ceria (Ce)-doped Fe3O4 nanoparticles (CeFe3O4) were synthesized via the hot-injection organic synthetic route in the presence of metal precursors and organic ligands. Thereafter, the organic-capped CeFe3O4 nanoparticles were surface-functionalized with amphiphilic polymers (Amp-poly) to render the nanoparticle stable, compact and biocompatible. Thiolated γ-cyclodextrin (γ-CD) was adsorbed on the Amp-poly-CeFe3O4 nanocomposite (NC) surface to form a γ-CD-Amp-poly-CeFe3O4 NC. γ-CD served both as a receptor and as a catalytic enhancer for TATP. Hemin (H), used as a catalytic signal amplifier was adsorbed on the γ-CD-Amp-poly-CeFe3O4 NC surface to form a γ-CD-Amp-poly-CeFe3O4–H NC that served as a functional nanozyme for the enhanced catalytic colorimetric detection of TATP. Under optimum experimental reaction conditions, TATP prepared in BIS-TRIS-Trisma Ac-KAc-NAc buffer, pH 3, was selectively and ultrasensitively detected without the need for acid hydrolysis based on the catalytic oxidation of 3,3′,5,5′-tetramethylbenzidine by H2O2 in the presence of the γ-CD-Amp-poly-CeFe3O4–H hybrid nanozyme. The obtained limit of detection of ∼0.05 μg/mL when compared with other published probes demonstrated superior sensitivity. The developed peroxidase mimic γ-CD-Amp-poly-CeFe3O4–H catalytic colorimetric sensor was successfully applied to detect TATP in soil, river water and tap water samples.