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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Hursthouse, Andrew
University of the West of Scotland
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2022Development of functional materials for the removal of heavy metals from industrial waste waters
- 2021Sustainable strategies for improved regulatory compliance within the food-processing sectorcitations
- 2019The potential of remedial techniques for hazard reduction of steel process by productscitations
- 2018Assessing PCB pollution in the Baltic Sea - An equilibrium partitioning based studycitations
- 2017Synthesis, characterization, and adsorptive properties of Fe3O4/GO nano-composites for antimony removalcitations
- 2016Study of spatial distribution of heavy metals in agricultural soils of El Tarf area (Northeast Algerian)
- 2016Alkyl Polyglycosides for Efficient Heat Transfer in Water Heating Systems
- 2015Equilibrium passive sampling as a tool to study polycyclic aromatic hydrocarbons in Baltic Sea sediment pore-water systemscitations
- 2010Measurement of arsenic and gallium content of gallium arsenide semiconductor waste streams by ICP-MScitations
- 2008Cobalt and secondary poisoning in the terrestrial food chaincitations
Places of action
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article
Assessing PCB pollution in the Baltic Sea - An equilibrium partitioning based study
Abstract
Sediment cores and bottom water samples from across the Baltic Sea region were analyzed for freely dissolved concentrations (Cfree), total sediment concentrations (CT) and the dissolved aqueous fraction in water of seven indicator PCBs. Ex-situ equilibrium sampling of sediment samples was conducted with polydimethylsiloxane (PDMS) coated glass fibers that were analyzed by automated thermal desorption GC-MS, which yielded PCB concentrations in the fiber coating (CPDMS). Measurements of CPDMS and CT were then applied to determine (i) spatially resolved freely dissolved PCB concentrations; (ii) baseline toxicity potential based on chemical activities (a); (iii) site specific mixture compositions; (iv) diffusion gradients at the sediment water interface and within the sediment cores; and (vi) site specific distribution ratios (KD). The contamination levels were low in the Gulf of Finland and moderate to elevated in the Baltic Proper, with the highest levels observed in the western Baltic Sea. The SPME method has been demonstrated to be an appropriate and sensitive tool for area surveys presenting new opportunities to study the in-situ distribution and thermodynamics of hydrophobic organic chemicals at trace levels in marine environments.