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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Kirkelund, Gunvor Marie
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2024Mapping circular economy practices for steel, cement, glass, brick, insulation, and wood – A review for climate mitigation modelingcitations
- 2022Influence of ash type and mixing methods on workability and compressive strength when using Greenlandic MSWI fly ash as cement replacement in mortar
- 2022Effects of Chlorides and Sulphates on Heavy Metal Leaching from Mortar with Raw and Electrodialytically Treated MSWI Fly Ashcitations
- 2021Impact of electrodialytic remediation of MSWI fly ash on hydration and mechanical properties of blends with Portland cementcitations
- 2020Screening of untreated municipal solid waste incineration fly ash for use in cement-based materials: chemical and physical propertiescitations
- 2019Characterization of sewage sludge ash and its effect on moisture physics of mortarcitations
- 2019Electrodialytically treated MSWI fly ash use in clay bricks
- 2019Screening Untreated Municipal Solid Waste Incineration Fly Ash for Use in Cement-Based Materials – Chemical and Physical Properties
- 2018Using polycarbobetaines for cu recovery from catholytes generated by electrodialytic treatment of sewage sludge ash
- 2017Colour, compressive strength and workability of mortars with an iron rich sewage sludge ashcitations
- 2016Wood ash used as partly sand and/or cement replacement in mortarcitations
- 2016Replacement of 5% of OPC by fly ash and APC residues from MSWI with electrodialytic pre-treatment
- 2015Ammonium citrate as enhancement for electrodialytic soil remediation and investigation of soil solution during the processcitations
- 2015Multivariate methods for evaluating the efficiency of electrodialytic removal of heavy metals from polluted harbour sedimentscitations
- 2014Electrodialytically treated MSWI APC residue as substitute for cement in mortar
- 2014The Aesthetical quality of SSA-containing mortar and concrete
- 2013Effect of pulse current on acidification and removal of Cu, Cd, and As during suspended electrodialytic soil remediationcitations
- 2012Electrodialytic remediation of suspended soil – Comparison of two different soil fractionscitations
- 2012Testing the possibility for reusing mswi bottom ash in Greenlandic road construction
- 2012Characterisation of MSWI bottom ash for potential use as subbase in Greenlandic road construction
- 2009Electrodialytic remediation of harbour sediment in suspension - Evaluation of effects induced by changes in stirring velocity and current density on heavy metal removal and pHcitations
- 2007Electrodialytic extraction of Cd and Cu from sediment from Sisimiut Harbour, Greenlandcitations
- 2005Acidification of Harbour sediment and removal of heavy metals induced by water splitting in electrodialytic remediation.citations
Places of action
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article
Ammonium citrate as enhancement for electrodialytic soil remediation and investigation of soil solution during the process
Abstract
Seven electrodialytic experiments were conducted using ammonium citrate as enhancing agent to remediate copper and chromium-contaminated soil from a wood-preservation site. The purpose was to investigate the effect of current density (0.2, 1.0 and 1.5 mA cm<sup>−2</sup>), concentration of enhancing agent (0.25, 0.5 and 1.0 M) and remediation times (21, 42 and 117 d) for the removal of Cu and Cr from a calcareous soil. To gain insight on metal behavior, soil solution was periodically collected using suction cups. It was seen that current densities higher than 1.0 mA cm<sup>−2</sup> did not increase removal and thus using too high current densities can be a waste of energy. Desorption rate is important and both remediation time and ammonium citrate concentration are relevant parameters. It was possible to collect soil solution samples following an adaptation of the experimental set-up to ensure continuous supply of ammonium citrate to the soil in order to keep it saturated during the remediation. Monitoring soil solution gives valuable information on the evolution of remediation and helps deciding when the soil is remediated.<br/>Final concentrations in the soil ranged from 220 to 360 mg Cu kg<sup>−1</sup> (removals: 78–86%) and 440–590 mg Cr kg<sup>−1</sup> (removals: 35–51%), being within the 500 mg kg<sup>−1</sup> limit for a clean soil only for Cu. While further optimization is still required for Cr, the removal percentages are the highest achieved so far, for a real Cu and Cr-contaminated, calcareous soil. The results highlight EDR potential to remediate metal polluted soils at neutral to alkaline pH by choosing a good enhancement solution.