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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Deen, Niels G.
Eindhoven University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (22/22 displayed)
- 2024Cyclic reduction of combusted iron powdercitations
- 2024Innovative Electrolytic Production of Iron Powder for the Circularity of Iron Fuel Cycle
- 2024Innovative Electrolytic Production of Iron Powder for the Circularity of Iron Fuel Cycle
- 2024On the formation of dendritic iron from alkaline electrochemical reduction of iron oxide prepared for metal fuel applicationscitations
- 2024On the formation of dendritic iron from alkaline electrochemical reduction of iron oxide prepared for metal fuel applicationscitations
- 2024Cyclic reduction of combusted iron powder:A study on the material properties and conversion reaction in the iron fuel cyclecitations
- 2024A Rotating Disc Electrochemical Reactor to Produce Iron Powder for the Co2-Free Iron Fuel Cycle
- 2024RUST-TO-GREEN IRON
- 2023Dendritic Iron Formation in Low-Temperature Iron Oxide Electroreduction Process using Alkaline Solution
- 2023Dendritic Iron Formation in Low-Temperature Iron Oxide Electroreduction Process using Alkaline Solution
- 2023Minimum fluidization velocity and reduction behavior of combusted iron powder in a fluidized bedcitations
- 2023Sintering behavior of combusted iron powder in a packed bed reactor with nitrogen and hydrogencitations
- 2023Comparative study of electroreduction of iron oxide using acidic and alkaline electrolytes for sustainable iron productioncitations
- 2023Comparative study of electroreduction of iron oxide using acidic and alkaline electrolytes for sustainable iron productioncitations
- 2023Regenerating Iron via Electrolysis for CO2-Free Energy Storage and Carrier
- 2022Electrochemical Reduction of Iron Oxide - Produced from Iron Combustion - for the Valorization of Iron Fuel Cycle
- 2022Reactiekinetiek van verbrand ijzerpoeder met waterstof ; Reduction kinetics of combusted iron powder using hydrogencitations
- 2022Reduction kinetics of combusted iron powder using hydrogencitations
- 2022Experimental Study of Iron Oxide Electroreduction with Different Cathode Material
- 2017Spray combustion analysis of huminscitations
- 2017Experimental and simulation study of heat transfer in fluidized beds with heat productioncitations
- 2012Experimental study of large scale fluidized beds at elevated pressurecitations
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article
On the formation of dendritic iron from alkaline electrochemical reduction of iron oxide prepared for metal fuel applications
Abstract
Low-temperature electrochemical reduction (electroreduction) of iron oxides is a promising alternative to the conventional methods for iron production due to its CO2-free operation and relatively low energy consumption. In this work, we demonstrate a novel approach for electrochemical iron production by promoting the formation of dendritic structures during iron electrodeposition, which facilitates the easy harvesting of deposits in powder form. Experiments were conducted using a single pair of parallel plate electrodes, immersed in a mixture of hematite (Fe2O3) powder and aqueous alkaline (NaOH) slurry. The effects of current density, Fe2O3 mass fraction, temperature, and powder size on current efficiency and deposit morphology are investigated. A large quantity of dendritic iron structures is observed when experiments are carried out without stirring and/or applying heat from a heating plate. This condition suggests temperature and (ion/species) concentration gradients in the system. The dendrites are mainly deposited on the cathode's sides, corners, and edges. Different deposits and dendritic structures (compact layer deposit, moss-like deposit, deposit with whisker-like dendrites, and deposit with crystal-like dendrites) are observed as operating conditions change. Overall, a cathodic deposition of metallic iron with a high Faradaic efficiency (≥90 %) is successfully accomplished. The present findings provide new insights into the production of electrolytic iron powder and its future use as a carbon neutral and sustainable fuel/energy carrier.