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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Cheng, Siyu
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Topics
Publications (7/7 displayed)
- 2024Thermodynamic re-optimisation of the CaO-SiO2 system integrated with experimental phase equilibria studiescitations
- 2023Experimental phase equilibria study and thermodynamic modelling of the “CuO0.5”-AlO1.5-SiO2 ternary system in equilibrium with metallic coppercitations
- 2022Iron ore sinter macro- and micro-structures, and their relationships to breakage characteristicscitations
- 2021Experimental phase equilibria studies in the “CuO0.5”-CaO-SiO2 ternary system in equilibrium with metallic coppercitations
- 2021Experimental phase equilibria studies in the FeO-Fe2O3-CaO-SiO2 system and the subsystems CaO-SiO2, FeO-Fe2O3-SiO2 in aircitations
- 2021Investigation of the thermodynamic stability of C(A, F)3 solid solution in the FeO-Fe2O3-CaO-Al2O3 System and SFCA Phase in the FeO-Fe2O3-CaO-SiO2-Al2O3 Systemcitations
- 2020Mechanisms of phase and microstructure formation during the cooling of "Fe2O3"-CaO-SiO2-Al2O3 melts in air and implications for iron ore sinteringcitations
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article
Experimental phase equilibria study and thermodynamic modelling of the “CuO0.5”-AlO1.5-SiO2 ternary system in equilibrium with metallic copper
Abstract
Phase equilibria studies were undertaken on the “CuO”-AlO-SiO system in equilibrium with metallic copper using equilibration and quenching technique followed by the electron probe X-ray microanalysis (EPMA). The liquidus of the “CuO”-AlO-SiO system, including the two 2-liquid miscibility gaps in the system as well as the cuprite (CuO), corundum (AlO), delafossite (CuAlO), tridymite and cristobalite (Si(CuAl)O), and mullite (AlSiO) primary phase fields has been characterized. New experimental results together with phase equilibria and thermodynamic literature data were used to obtain a self-consistent set of parameters of the thermodynamic model for all phases. The liquidus projection of the “CuO”-AlO-SiO system was presented for the first time in the full range of temperatures and compositions. It was found that the simultaneous dissolution of a small amount of alumina and copper oxide (CuAlO) in SiO phases stabilize cristobalite over tridymite at low temperatures.