People | Locations | Statistics |
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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Shevchenko, Maxim
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (48/48 displayed)
- 2024Phase equilibria and thermodynamic modelling of the PbO-ZnO-FeO-FeO1.5-SiO2 system and its subsystems in equilibrium with air/metallic lead/ironcitations
- 2024Analysis of slag chemistry in WEEE smelting using experimental and modelling study of the “CuO0.5”-ZnO-FeO-FeO1.5-CaO-SiO2-AlO1.5 system in equilibrium with Cu metalcitations
- 2024Integrated Experimental Phase Equilibria and Thermodynamic Modelling Research and Implementation in support of progress of process pyrometallurgy towards sustainability
- 2024Thermodynamic re-optimisation of the CaO-SiO2 system integrated with experimental phase equilibria studiescitations
- 2024Integrated experimental and thermodynamic modeling study of slag-matte-metal equilibrium in the Pb–Fe–O–S–Si-(Al, Ca, Zn) systems at 1100–1200 °Ccitations
- 2024Experimental and thermodynamic modeling study of phase equilibria in the PbO–NiO–SiO<sub>2</sub> systemcitations
- 2024Phase equilibria in the ZnO-MgO-SiO2 and PbO-ZnO-MgO-SiO2 systems for characterizing MgO-based refractory – slag interactionscitations
- 2023Experimental phase equilibria study and thermodynamic modelling of the “CuO0.5”-AlO1.5-SiO2 ternary system in equilibrium with metallic coppercitations
- 2023Phase equilibria and thermodynamic modelling of the PbO–ZnO-“CuO0.5”-SiO2 systemcitations
- 2023Experiment and thermodynamic modelling of phase equilibria in PbO−“CuO0.5” and PbO−“CuO0.5”−“FeO1.5” slag systems with metalcitations
- 2023Integrated Experimental Phase Equilibria and Thermodynamic Modelling Research and Implementation in Support of Sustainable Pyrometallurgical Processingcitations
- 2023Experimental Study of the Combined Effects of Al2O3, CaO and MgO on Gas/Slag/Matte/Spinel Equilibria in the Cu–Fe–O–S–Si–Al–Ca–Mg System at 1473 K (1200ºC) and p(SO2) = 0.25 atmcitations
- 2023Development of experimental techniques for the phase equilibrium study in the Pb-Fe-O-S-Si system involving gas, slag, matte, lead metal and tridymite phasescitations
- 2022Integrated phase equilibria experimental study and thermodynamic modeling of the Cr–Si–O, Fe–Cr–O and Fe–Cr–Si–O systemscitations
- 2022Integrated experimental and thermodynamic modeling investigation of phase equilibria in the PbO–MgO–SiO2 system in aircitations
- 2022Integrated experimental and thermodynamic modeling study of phase equilibria in the ‘CuO0.5’-MgO-SiO2 system in equilibrium with liquid Cu metal for characterizing refractory-slag interactionscitations
- 2022Experimental study, thermodynamic calculations and industrial implications of slag/matte/metal equilibria in the Cu–Pb–Fe–O–S–Si systemcitations
- 2022Experimental phase equilibria study and thermodynamic modelling of the PbO-“FeO”-SiO2-ZnO, PbO-“FeO”-SiO2-Al2O3 and PbO-“FeO”-SiO2-MgO systems in equilibrium with metallic Pb and Fecitations
- 2022Experimental study of the Cu2O-FeOx-CaO system in equilibrium with metallic copper at 1200 °C to 1300 °C and at P(O2)s = 10−5 to 10−7 Atmcitations
- 2021Experimental phase equilibria studies in the “CuO0.5”-CaO-SiO2 ternary system in equilibrium with metallic coppercitations
- 2021Integrated experimental phase equilibria study and thermodynamic modelling of the binary ZnO–Al2O3, ZnO–SiO2, Al2O3–SiO2 and ternary ZnO–Al2O3–SiO2 systemscitations
- 2021Experimental phase equilibria study and thermodynamic modelling of the PbO-“FeO”-SiO2, PbO-“FeO”-CaO and PbO-“FeO”-CaO-SiO2 Systems in Equilibrium with Metallic Pb and Fecitations
- 2021Experimental phase equilibria studies in the FeO-Fe2O3-CaO-SiO2 system and the subsystems CaO-SiO2, FeO-Fe2O3-SiO2 in aircitations
- 2021Experimental study of “CuO0.5”-“FeO”-SiO2 and “FeO”-SiO2 systems in equilibrium with metal at 1400–1680 °Ccitations
- 2021Investigation of the thermodynamic stability of C(A, F)3 solid solution in the FeO-Fe2O3-CaO-Al2O3 System and SFCA Phase in the FeO-Fe2O3-CaO-SiO2-Al2O3 Systemcitations
- 2021Integrated experimental phase equilibria study and thermodynamic modeling of the PbO–SnO–SnO2–SiO2 system in air and in equilibrium with Pb–Sn metalcitations
- 2021Integrated experimental liquidus and modelling studies of the ternary AgO0.5-FeO1.5-SiO2 system in equilibrium with metallic Agcitations
- 2020Experimental measurement and thermodynamic model predictions of the distributions of Cu, As, Sb and Sn between liquid lead and PbO–FeO–Fe2O3–SiO2 slagcitations
- 2020Experimental liquidus studies of the ZnO-“CuO0.5” and ZnO-“CuO0.5”-SiO2 liquidus in equilibrium with Cu-Zn metalcitations
- 2020Thermodynamic optimization of the binary PbO-“Cu2O”, “Cu2O”-SiO2 and ternary PbO-“Cu2O”-SiO2 systemscitations
- 2020Experimental study and thermodynamic optimization of the ZnO–FeO–Fe2O3–CaO–SiO2 systemcitations
- 2019Experimental liquidus studies of the CaO-ZnO-Fe2O3 system in aircitations
- 2019A Phase Equilibrium of the Iron-rich Corner of the CaO–FeO–Fe2O3–SiO2 System in Air and the Determination of the SFC Primary Phase Fieldcitations
- 2019Experimental liquidus study of the binary PbO-CaO and ternary PbO-CaO-SiO2 systemscitations
- 2019Experimental liquidus studies of the Zn-Fe-Si-O system in aircitations
- 2019Experimental liquidus studies of the Pb-Fe-Ca-O system in aircitations
- 2019Thermodynamic optimization of the PbO–FeO–Fe2O3–SiO2 systemcitations
- 2019Effect of Gas Atmosphere on the Phase Chemistry in the CaO-FeO-Fe2O3-SiO2 System Related to Iron Ore Sinter-makingcitations
- 2019Experimental liquidus study of the ternary CaO-ZnO-SiO2 systemcitations
- 2019Experimental Study and Thermodynamic Calculations of the Distribution of Ag, Au, Bi, and Zn Between Pb Metal and Pb–Fe–O–Si slagcitations
- 2019Experimental liquidus study of the binary PbO-ZnO and ternary PbO-ZnO-SiO2 systemscitations
- 2019Integrated experimental and thermodynamic modelling research for primary and recycling pyrometallurgy
- 2019Experimental liquidus studies of the binary Pb-Cu-O and ternary Pb-Cu-Si-O systems in equilibrium with metallic Pb-Cu alloyscitations
- 2019Experimental Liquidus Studies of the Pb-Fe-Si-O System in Aircitations
- 2019Experimental and thermodynamic modelling study of the effects of Al2O3, CaO AND MgO impurities on gas/slag/matte/spinel equilibria in the “Cu2O”-“FeO”-SiO2-S-Al2O3-CaO-MgO system
- 2018Experimental liquidus studies of the Pb-Fe-Si-O system in equilibrium with metallic Pbcitations
- 2018Development of a thermodynamic database for the multicomponent PbO-“Cu2O”-FeO-Fe2O3-ZnO-CaO-SiO2 system for pyrometallurgical smelting and recyclingcitations
- 2018Experimental liquidus studies of the Pb-Cu-Si-O system in equilibrium with metallic Pb-Cu alloyscitations
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article
Integrated experimental and thermodynamic modeling study of phase equilibria in the ‘CuO0.5’-MgO-SiO2 system in equilibrium with liquid Cu metal for characterizing refractory-slag interactions
Abstract
An integrated experimental and thermodynamic modeling study of the phase equilibria in the ‘CuO’-MgO-SiO system in equilibrium with liquid Cu metal has been undertaken to better understand the reactions between MgO-based refractories and liquid slag in copper converting and refining processes. New experimental phase equilibria data at 1250–1680 °C were obtained for this system using a high-temperature equilibration of synthetic mixtures with predetermined compositions in silica ampoules or magnesia crucibles, a rapid quenching technique, and electron probe X-ray microanalysis of the equilibrated phase compositions. The system has been shown to contain primary phase fields of cristobalite (SiO), tridymite (SiO), pyroxene/protoenstatite (MgSiO), olivine/forsterite (MgSiO), periclase (MgO), and cuprite (CuO). Three regions of 2-liquid immiscibility were found—two in the high-silica range of compositions above the cristobalite primary phase field (close to ‘CuO’-SiO and MgO–SiO binaries) and one in the low-SiO, high-‘CuO’ compositional region above the periclase and olivine phase fields. The results obtained in this study indicate that silica in high-copper refining slags likely led to olivine and pyroxene phase formation, increased solubility of MgO in liquid slag, and decline in the performance of MgO-based refractories. New experimental data were used in the development of a thermodynamic database describing this pseudo-ternary system.