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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Abdeyazdan, Hamed
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (6/6 displayed)
- 2024Integrated experimental and thermodynamic modeling study of slag-matte-metal equilibrium in the Pb–Fe–O–S–Si-(Al, Ca, Zn) systems at 1100–1200 °Ccitations
- 2024Experimental and thermodynamic modeling study of phase equilibria in the PbO–NiO–SiO<sub>2</sub> systemcitations
- 2024Phase equilibria in the ZnO-MgO-SiO2 and PbO-ZnO-MgO-SiO2 systems for characterizing MgO-based refractory – slag interactionscitations
- 2022Integrated experimental and thermodynamic modeling investigation of phase equilibria in the PbO–MgO–SiO2 system in aircitations
- 2022Integrated experimental and thermodynamic modeling study of phase equilibria in the ‘CuO0.5’-MgO-SiO2 system in equilibrium with liquid Cu metal for characterizing refractory-slag interactionscitations
- 2021Integrated experimental phase equilibria study and thermodynamic modeling of the PbO–SnO–SnO2–SiO2 system in air and in equilibrium with Pb–Sn metalcitations
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article
Integrated experimental and thermodynamic modeling study of phase equilibria in the ‘CuO0.5’-MgO-SiO2 system in equilibrium with liquid Cu metal for characterizing refractory-slag interactions
Abstract
An integrated experimental and thermodynamic modeling study of the phase equilibria in the ‘CuO’-MgO-SiO system in equilibrium with liquid Cu metal has been undertaken to better understand the reactions between MgO-based refractories and liquid slag in copper converting and refining processes. New experimental phase equilibria data at 1250–1680 °C were obtained for this system using a high-temperature equilibration of synthetic mixtures with predetermined compositions in silica ampoules or magnesia crucibles, a rapid quenching technique, and electron probe X-ray microanalysis of the equilibrated phase compositions. The system has been shown to contain primary phase fields of cristobalite (SiO), tridymite (SiO), pyroxene/protoenstatite (MgSiO), olivine/forsterite (MgSiO), periclase (MgO), and cuprite (CuO). Three regions of 2-liquid immiscibility were found—two in the high-silica range of compositions above the cristobalite primary phase field (close to ‘CuO’-SiO and MgO–SiO binaries) and one in the low-SiO, high-‘CuO’ compositional region above the periclase and olivine phase fields. The results obtained in this study indicate that silica in high-copper refining slags likely led to olivine and pyroxene phase formation, increased solubility of MgO in liquid slag, and decline in the performance of MgO-based refractories. New experimental data were used in the development of a thermodynamic database describing this pseudo-ternary system.