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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ke, Xinyuan
University of Bath
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Improving the pozzolanic reactivity of clay, marl and obsidian through mechanochemical or thermal activationcitations
- 2023Carbonation Rate of Alkali-Activated Concretes
- 2023RILEM TC 281-CCC Working Group 6
- 2023Development and characterisation of an alginate and expanded graphite based composite for thermochemical heat storagecitations
- 2022The impact of mechanochemical activation on the physicochemical properties and pozzolanic reactivity of kaolinite, muscovite and montmorillonitecitations
- 2022Biomass Bottom Ash as Supplementary Cementitious Material: The Effect of Mechanochemical Pre-Treatment and Mineral Carbonationcitations
- 2022Carbonation rate of alkali-activated concretes and high-volume SCM concretescitations
- 2021Activator Anion Influences the Nanostructure of Alkali-Activated Slag Cementscitations
- 2020Incorporation of strontium and calcium in geopolymer gelscitations
- 2019Layered double hydroxides modify the reaction of sodium silicate-activated slag cementscitations
- 2018Slag and Activator Chemistry Control the Reaction Kinetics of Sodium Metasilicate-Activated Slag Cementscitations
- 2018Metakaolin-based geopolymers for nuclear waste encapsulationcitations
- 2017Alternative inorganic binders based on alkali-activated metallurgical slagscitations
- 2017Characterization of supplementary cementitious materials by thermal analysiscitations
Places of action
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article
The impact of mechanochemical activation on the physicochemical properties and pozzolanic reactivity of kaolinite, muscovite and montmorillonite
Abstract
<p>Partially replacing cement clinkers with activated clays is one of the most promising routes to decarbonise the cement industry and tackle the climate change crisis. This study systematically investigated the impact of mechanochemical activation on the physicochemical properties of kaolinite, muscovite and montmorillonite clays, including particle size distributions, morphologies, bulk and surface chemical structures. The results suggest that mechanochemical activation treatment is particularly efficient for improving the pozzolanic activity of 2:1 clays (i.e. muscovite and montmorillonite), which are difficult to effectively activate through thermal treatments and therefore not previously been extensively used as supplementary cementitious materials (SCMs). In addition to dehydroxylation and amorphisation, mechanochemical milling also leads to surface aluminium enrichment and reduction in binding energies of both Si and Al elements, all contributing to the enhanced pozzolanic reactivity. The outcome from this study represents a step-change in scientific knowledge and extends frontiers of developing new SCMs from sustainable resources.</p>